Diastereoselective reduction of β-ketophosphonates derived from amino acids.: A new entry to enantiopure β-hydroxy-γ-aminophosphonate derivatives

被引：32

作者：

Ordóñez, M ^{[1
]}

de la Cruz, R ^{[1
]}

Fernández-Zertuche, M ^{[1
]}

Muñoz-Hernández, MA ^{[1
]}

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(02)00159-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of gamma-N,N-dibenzylamino-beta-ketophosphonates 4 derived from readily available (S)-tribenzylated amino acids teas achieved with catecholborane at -20degreesC affording gamma-amino-beta-hydroxyphosphonates 5 in high diastereoselectivity and good chemical yield. These reactions provide a new entry to enantiomerically pure gamma-amino-beta-hydroxyphosphonates. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：559 / 562

页数：4

共 28 条

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Monique Calmès
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CHEMISTRY LETTERS, 1973, (02) : 185 - 186
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