Hydrothermal synthesis, crystal structure, thermal behaviour, IR and Raman spectroscopy of Na3Y(CO3)3.6 H2O

被引：4
|
作者：
Ben Ali, A
Awaleh, MO
Leblanc, M
Smiri, LS
Maisonneuve, V
Houlbert, S
机构：
[1] Univ Maine, Fac Sci, CNRS, UMR 6010,Lab Oxydes & Fluorures, F-72085 Le Mans 9, France
[2] Fac Sci Bizerte, Lab Chim Inorgan & Struct, Jarzouna 7021, Tunisia
[3] Univ Maine, CNRS, UMR 6087, Fac Sci,Lab Phys Etat Condense, F-72085 Le Mans 9, France
来源：
COMPTES RENDUS CHIMIE | 2004年 / 7卷 / 6-7期
关键词：
carbonate; x-ray diffraction; IR; Raman;
D O I：
10.1016/j.crci.2004.03.007
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new sodium yttrium carbonate hydrate, Na3Y(CO3)(3).6 H2O, is prepared by hydrothermal synthesis and characterized by single crystal X-ray diffraction, thermal analysis, IR and Raman spectroscopy. Na3Y(CO3)(3).6 H2O crystallizes in the hexagonal system, space group P6(3); a = 11.347(5) Angstrom, c = 5.935(5) Angstrom; V = 661.8(5) Angstrom(3); Z = 2. Refinements yield R(F-2) = 0.058 and R-w(F-2) = 0.161 for 692 unique reflections. The structure is built up from [YO3+3+3] polyhedra surrounded by [NaO6] octahedra. Carbonate groups form infinite layers at z = 0.175 and z = 0.675. Dehydration of Na3Y(CO3)(3).6 H2O yields an amorphous carbonate. (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.
引用
收藏
页码：661 / 668
页数：8
相关论文
共 50 条
  • [21] Crystal structure of a novel complex [Co(3,3′-bpbc)(H2O)3]·H2O
    E. -J. Gao
    L. -L. Jiang
    D. Zhang
    W. Jiao
    T. -L. Liu
    Y. -J. Zhang
    G. -L. Wu
    J. Xu
    Journal of Structural Chemistry, 2013, 54 : 978 - 982
  • [22] The crystal structure of galgenbergite-(Ce), CaCe2(CO3)4 H2O
    Walter, Franz
    Bojar, Hans-Peter
    Hollerer, Christine E.
    Mereiter, Kurt
    MINERALOGY AND PETROLOGY, 2013, 107 (02) : 189 - 199
  • [23] The crystal structure of galgenbergite-(Ce), CaCe2(CO3)4∙H2O
    Franz Walter
    Hans-Peter Bojar
    Christine E. Hollerer
    Kurt Mereiter
    Mineralogy and Petrology, 2013, 107 : 189 - 199
  • [24] Hydrothermal synthesis and crystal structure of Na2In2[PO3(OH)]4 • H2O with a new structure type
    Mi, JX
    Huang, YX
    Mao, SY
    Huang, XD
    Wei, ZB
    Huang, ZL
    Zhao, JT
    JOURNAL OF SOLID STATE CHEMISTRY, 2001, 157 (01) : 213 - 219
  • [25] Preparation, crystal structure, thermal decomposition, and vibrational spectra of [Co(NH3)6]2[Be4O(CO3)6] • 10 H2O
    Dahm, M
    Adam, A
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (02): : 494 - 501
  • [26] HYDROTHERMAL INVESTIGATION OF SYSTEMS Y2O3-H2O-NA2O Y2O3-D2O-NA2O Y2O3-H2O AND Y2O3-H2O-NH3 . CRYSTAL STRUCTURE OF Y (OH)3
    CHRISTENSEN, AN
    HAZELL, RG
    NILSSON, A
    ACTA CHEMICA SCANDINAVICA, 1967, 21 (02): : 481 - +
  • [27] Synthesis and structure of hydrated yttrium carbonate, Y2(CO3)3•2.79H2O
    Liu, S
    Ma, RJ
    Jiang, RY
    Luo, FC
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2000, 30 (02): : 271 - 279
  • [28] Synthesis, crystal structure and fluorescence properties of complex [Co(Hdhpmy)(H2O)3]•3H2O
    Pan Zhao-Rui
    Ren Jun-Cai
    Ma Mei-Hua
    Meng He-Gen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (02) : 280 - 284
  • [29] Infrared spectroscopy of CO3•- (H2O)1,2 and CO4•- (H2O)1,2
    Muenst, Maximilian G.
    Oncak, Milan
    Beyer, Martin K.
    van der Linde, Christian
    JOURNAL OF CHEMICAL PHYSICS, 2021, 154 (08):
  • [30] Synthesis and crystal structure of dicesium trans-dicarbonatotetraaquomagnesium, Cs2[Mg(CO3)2(H2O)4]
    Zheng, YQ
    Adam, A
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 1999, 15 (03) : 211 - 217
12345