AgI-Directed Triple-Stranded Helicates with meta-Ethynylpyridine Ligands

被引：11
|
作者：
Li, Qiaolian [1 ]
Huang, Fu [2 ]
Fan, Yaxun [2 ]
Wang, Yilin [2 ]
Li, Jianfeng [1 ]
He, Yujian [1 ]
Jiang, Hua [2 ,3 ]
机构：
[1] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[3] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 20期
基金：
中国国家自然科学基金;
关键词：
Helical structures; Self-assembly; Structure elucidation; Ligand design; Silver; X-RAY-STRUCTURE; SUPRAMOLECULAR CYLINDERS; LANTHANIDE HELICATE; COORDINATION SITES; DNA; DINUCLEAR; BINDING; ENCAPSULATION; RECOGNITION; CHEMISTRY;
D O I：
10.1002/ejic.201402345
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of triple-stranded complexes, [1a(3)Ag] BF4, [1b(3)Ag]BF4, [2a(3)Ag(2)](BF4)(2), [2b(3)Ag(2)](BF4)(2), and [3(3)Ag(3)](BF4)(3), have been obtained through the self-assembly of Ag-I ions with p-phenylene ethynylpyridine ligands. X-ray crystallographic studies unambiguously demonstrated a Ag-I-directed monodentate triple-stranded helical structure in the solid state for 1b and 2b. A combination of NMR spectroscopy, HRMS (ESI), and isothermal titration microcalorimetry studies further confirmed that strands 1, 2, and 3 are also able to form triple-stranded helical structures in the presence of Ag-I ions in solution.
引用
收藏
页码：3235 / 3244
页数：10
相关论文
共 50 条
  • [41] Sulfate Donor Based Dinuclear Heteroleptic Triple-Stranded Helicates from Sulfite and Ditopic Nitrogen Donor Ligands and Their Transformation to Dinuclear Homoleptic Double-Stranded Mesocates
    Soumya, K. R.
    Arumugam, Ramar
    Shankar, Bhaskaran
    Sathiyendiran, Malaichamy
    INORGANIC CHEMISTRY, 2018, 57 (17) : 10718 - 10725
  • [42] Dinuclear triple-stranded helicates from rigid oligo-p-phenylene ligands:: Self-assembly and ligand self-recognition
    Albrecht, M
    Schneider, M
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (06) : 1301 - 1306
  • [43] Design, Synthesis, and Structural Characterization of a New Class of Ferrocene-Containing Heterometallic Triple-Stranded Helicates
    Raja, Muthukrishna
    Iyer, Ratnasabapathy G.
    Gwengo, Chengeto
    Reger, Daniel L.
    Pellechia, Perry J.
    Smith, Mark D.
    Pascui, Andrea E.
    ORGANOMETALLICS, 2013, 32 (01) : 95 - 103
  • [44] Lanthanide triple-stranded helicates:: Controlling the yield of the heterobimetallic species (vol 45, pg 7807, 2006)
    Jensen, Thomas B.
    Scopelliti, Rosario
    Bunzli, Jean-Claude G.
    INORGANIC CHEMISTRY, 2007, 46 (04) : 1507 - 1507
  • [45] Dinuclear Triple-Stranded Helicates Composed of Tetradentate Ligands with Aluminum(III) Chromophores: Optical Resolution and Multi-color Circularly Polarized Luminescence Properties
    Ono, Toshikazu
    Ishihama, Kohei
    Taema, Ai
    Harada, Takunori
    Furusho, Kiyonao
    Hasegawa, Masashi
    Nojima, Yuki
    Abe, Masaaki
    Hisaeda, Yoshio
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (05) : 2614 - 2618
  • [46] Self-assembly of dinuclear double- and triple-stranded helicates from bis(bipyridine) ligands derived from Troger's base analogues
    Kiehne, Ulf
    Weilandt, Torsten
    Luetzen, Arne
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (12) : 2056 - 2064
  • [47] A simple thermodynamic model for rationalizing the formation of self-assembled multimetallic edifices: Application to triple-stranded helicates
    Zeckert, K
    Hamacek, J
    Rivera, JP
    Floquet, S
    Pinto, A
    Borkovec, M
    Piguet, C
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (37) : 11589 - 11601
  • [48] Unraveling the Remarkable Influence of Substituents on the Emission Variation and Circularly Polarized Luminescence of Dinuclear Aluminum Triple-Stranded Helicates
    Ueno, Kodai
    Konishi, Yuto
    Cui, Luxia
    Harada, Takunori
    Ishibashi, Kohei
    Konta, Takeru
    Muranaka, Atsuya
    Hisaeda, Yoshio
    Hoshino, Yu
    Ono, Toshikazu
    INORGANIC CHEMISTRY, 2024, 63 (14) : 6296 - 6304
  • [49] Diastereoselective self-assembly of double- and triple-stranded helicates from a D-isomannide derivative
    Kiehne, U.
    Lutzen, A.
    ORGANIC LETTERS, 2007, 9 (26) : 5333 - 5336
  • [50] Dinuclear triple-stranded complexes of ReV with bis(benzene-o-dithiolato) ligands
    Gancheff, Jorge S.
    Hahn, F. Ekkehardt
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 98 : 62 - 69
12345