Enantioselective Reduction of Prochiral Ketones Employing Sprouted Pisum sativa as Biocatalyst

被引：18
|
作者：
Yadav, Jhillu S. [1 ]
Reddy, Basi V. Subba [1 ]
Sreelakshmi, Chittamuru [1 ]
Rao, Adari Bhaskar [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNTHESIS-STUTTGART | 2009年 / 11期
关键词：
biocatalysis; ketones; enantioselective; chiral alcohols; STEREOSELECTIVE REDUCTION; ASYMMETRIC REDUCTION; CHIRAL ALCOHOLS; OXIDATION; ROOT;
D O I：
10.1055/s-0028-1088047
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sprouted green peas have been used for the first time as biocatalysts for enantioselective reduction of prochiral ketones. The reactions are highly enantioselective to furnish chiral alcohols in good yields. The sprouted peas as biocatalysts are a cheap and easy way for generating some interesting chiral alcohols. This process is efficient and convenient to produce chiral secondary alcohols in water.
引用
收藏
页码：1881 / 1885
页数：5
相关论文
共 50 条
  • [21] A new family of modular chiral ligands for the catalytic enantioselective reduction of prochiral ketones
    Puigjaner, C
    Vidal-Ferran, A
    Moyano, A
    Pericàs, MA
    Riera, A
    JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (21): : 7902 - 7911
  • [22] ASYMMETRIC REDUCTION OF PROCHIRAL KETONES
    CAILLE, JC
    BULLIARD, M
    LABOUE, B
    CHIMICA OGGI-CHEMISTRY TODAY, 1995, 13 (4-5) : 17 - 20
  • [23] Enantioselective reductions of prochiral ketones by means of oxazaborolidines
    Taraba, M
    Palecek, J
    CHEMICKE LISTY, 1997, 91 (01): : 9 - 22
  • [24] New Anti-Prelog Stereospecific Whole-Cell Biocatalyst for Asymmetric Reduction of Prochiral Ketones
    Wang, Min-Yu
    Cai, Shun-Ju
    Lin, Jia-Chun
    Ji, Xiao-Jun
    Zhang, Zhi-Gang
    MOLECULES, 2023, 28 (03):
  • [25] Enantioselective reduction of prochiral ketones promoted by amino amide ruthenium complexes: A DFT study
    Meftah, Y.
    Boumedjane, Y.
    Fleurat-Lessard, P.
    Delbecq, F.
    Michel, C.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2021, 939
  • [26] Synthesis of chiral oxetanes via the enantioselective reduction of prochiral 2-halogenated ketones
    Rodriguez, Jennifer M. Garcia
    Hernandez, Javier Lopez
    Diaz, Blanca Quinones
    Santiago, Kiara
    Espinosa-Diaz, Sandraliz
    Ortiz-Marciales, Margarita
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [27] ENANTIOSELECTIVE REDUCTION OF PROCHIRAL KETONES - USE OF ALKYL ALUMINUM DERIVED FROM NATURAL ISOPRENOIDS
    GIACOMELLI, G
    FALORNI, M
    FRANCESCHINI, R
    CHIMICA & L INDUSTRIA, 1984, 66 (10): : 649 - 650
  • [28] Synthesis of chiral oxetanes via the enantioselective reduction of prochiral 2-halogenated ketones
    Quinones, Blanca I.
    Ortiz, Margarita
    Martinez, Ileanne
    Santiago, Kiara
    Laguna, Rebecca
    Rivera, Javier
    Guzman, Irisbel
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [29] Enantioselective reduction of prochiral ketones promoted by amino amide ruthenium complexes: A DFT study
    Meftah, Y.
    Boumedjane, Y.
    Fleurat-Lessard, P.
    Delbecq, F.
    Michel, C.
    Journal of Organometallic Chemistry, 2021, 939
  • [30] Enantioselective Reduction of Prochiral Ketones Catalyed by Oxazaborolidine Derived from L-Cystine
    Xing Shu Li
    Xiao Ling Zhang
    Ru Gang Xie(Department of Chemistry
    Chinese Chemical Letters, 1997, (08) : 679 - 680
12345