Nickel geochemistry of oil sands fluid petroleum coke deposits, Alberta, Canada

Nickel (Ni) leaching from oil sands petroleum coke can have toxicological effects on aquatic organisms. However, geochemical controls on Ni release, transport, and attenuation within coke deposits remains limited. We examined the geochemistry of fluid coke and associated pore waters from two deposits at an oil sands mine near Fort McMurray, Alberta, Canada. Synchrotron-based microX-ray fluorescence (mu XRF) and micro-X-ray absorption near edge structure (mu XANES) spectroscopy show that Ni(II)-porphyrin complexes dominate, but inorganic phases including Ni(II)-sulfide and Ni(II)-oxide comprise a minor component of fluid coke. Sequential chemical extractions suggested that sorption-desorption reactions may influence Ni mobility within fluid coke deposits. Although only a small proportion of total Ni (< 4%) is susceptible to leaching under environmentally relevant concentrations, dissolved Ni concentrations (n = 65) range from 2 to 120 mu g.L-1 (median 7.8 mu g.L-1) within the two deposits and generally decrease with depth below the water table. Pore water Ni concentrations are negatively correlated with pH, but not with dissolved sulfate, bicarbonate, or chloride. Overall, our findings suggest that pore water pH and sorption-desorption reactions are principal controls on dissolved Ni concentrations within oil sands fluid petroleum coke deposits.