Preparation, Crystal Structure, and Thermal Decomposition of a Novel Nitrogen-rich Compound Zn3(ATZ)6(N3)6 ( ATZ=4-amino-1,2,4-triazole, N%=61.7%)

被引：16
|
作者：
Tong, Wen-Chao [1 ]
Yang, Li [1 ]
Wu, Bi-Dong [1 ]
Zhang, Tong-Lai [1 ]
机构：
[1] Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 05期
关键词：
4-Amino-1; 2; 4-triazole; Zinc; Azides; Crystal structure; Decomposition; ENERGETIC SALTS; AZIDE; POLYMERS; COMPLEX;
D O I：
10.1002/zaac.201300502
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The green nitrogen-rich coordination compound Zn-3(ATZ)(6)(N-3)(6) (1) (ATZ = 4-amino-1,2,4-triazole) was prepared and characterized by elemental analysis, IR spectroscopy, DSC and TG/DTG analyses. Its crystal structure was determined through X-ray single crystal diffraction at 153(2) K. The crystal belongs to the monoclinic P2(1)/n space group with crystal parameters of the unit cell dimensions: a = 0.9187(3) nm, b = 1.4109(4) nm, c = 1.3395(4) nm, = 92.593(4)degrees, V = 1.7345(8) nm(3), Z = 4, D-c = 1.824 gcm(-3). The kinetic parameters of the first exothermic process of 1 were studied by the Kissinger's method and Ozawa-Doyle's method. Sensitivity tests revealed that 1 is insensitive to mechanical stimuli.
引用
收藏
页码：980 / 985
页数：6
相关论文
共 50 条
  • [31] Zinc(II) and copper(II) complexes with N-substituted imines derived from 4-amino-1,2,4-triazole: Synthesis, crystal structure, and biological activity
    Bazhina, Evgeniya S.
    Bovkunova, Anna A.
    Shmelev, Maxim A.
    Korlyukov, Alexander A.
    Pavlov, Alexander A.
    Hochvaldova, Lucie
    Kvitek, Libor
    Panacek, Ales
    Kopel, Pavel
    Eremenko, Igor L.
    Kiskin, Mikhail A.
    INORGANICA CHIMICA ACTA, 2023, 547
  • [32] 1,2,4-TRIAZOLE COMPLEXES .6. CRYSTAL-STRUCTURE OF TRIS-MU-(4-METHYL-1,2,4-TRIAZOLE-N1,N2)-BIS[(4-METHYL-1,2,4-TRIAZOLE-N1)BIS(THIOCYANATO-N)MANGANESE(II)],MN2(C3H5N3)5(NCS)4
    ENGELFRIET, DW
    VERSCHOOR, GC
    VERMIN, WJ
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (DEC): : 2927 - 2931
  • [33] PREPARATION AND STRUCTURE INVESTIGATION OF [N(C6H5)(CH3)3]2CA(N3)4
    MAUTNER, FA
    KRISCHNER, H
    KRATKY, C
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1986, 176 (1-2): : 85 - 90
  • [34] 5-AMINO-1-BUTYL-3-(N-BUTYL-N',N'-DIBENZOYLHYDRAZINO)-1,2,4-TRIAZOLE, C24H30N6O2
    RECK, G
    CZUGLER, M
    PARKANYI, L
    SAUER, E
    CRYSTAL STRUCTURE COMMUNICATIONS, 1981, 10 (02): : 565 - 570
  • [35] Synthesis and crystal structure of a novel polymeric lead(II) compound:: [Pb2(phen)2(N3)3(ClO4)]n
    Marandi, Farzin
    Mirtamizdoust, Babak
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (09): : 1329 - 1332
  • [36] Electrochemical and quantum chemical studies of 3,5-di(n-tolyl)-4-amino-1,2,4-triazole adsorption on mild steel in acidic media
    Bentiss, F
    Lagrenée, M
    Elmehdi, B
    Mernari, B
    Traisnel, M
    Vezin, H
    CORROSION, 2002, 58 (05) : 399 - 407
  • [37] Synthesis and Crystal Structure of Compound〔Zn （S6） （CH3C5H4N）2〕
    Hong-Jun (Department of Chemistry
    Wu Xin-Tao (State Key Laboratory of Structural Chemistry
    结构化学, 1995, (Z1) : 369 - 372
  • [38] Synthesis and characterization of 3,3′-azobis(6-amino-1,2,4,5-tetrazine) DAAT -: A new promising nitrogen-rich compound
    Kerth, J
    Löbbecke, S
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2002, 27 (03) : 111 - 118
  • [39] Crystal structure of 3-propyl-6-aryl-7-p-methoxybenzyldiene-1,2,4-triazole[3,4-b]-1,2,4-thiadiazine, C21H20N4OS
    Thomas, LM
    Kalluraya, B
    Holla, BS
    Shiridhara, K
    Ramasubbu, N
    Bhandary, KK
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (01): : 57 - 58
  • [40] Hydrothermal syntheses and structures of a novel zincophosphite, [C6N2H18] • [Zn3(HPO3)4]
    Fu, WS
    Zhang, D
    Shi, Z
    Yang, L
    Feng, SH
    INORGANICA CHIMICA ACTA, 2006, 359 (01) : 369 - 373
12345