Photosensitized oxygenation of alkenes in the presence of bisazafullerene (C59N)2 and hydroazafullerene C59HN

被引:0
|
作者
Tagmatarchis, N [1 ]
Shinohara, H [1 ]
机构
[1] Nagoya Univ, Dept Chem, Nagoya, Aichi 4648602, Japan
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中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Bisazafullerene (C59N)(2) and hydroazafullerene C59HN photosensitize the reaction of alkenes with oxygen. 2-methyl 2-butene and alpha-terpinene undergo ene and Diels-Alder photooxygenation reactions, respectively, in the presence of minute amounts of azafullerenes to produce the corresponding peroxides.
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页码:413 / 416
页数:4
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