Electron paramagnetic resonance of Gd3+ ion in monocrystal YAl3(BO3)4

被引：16
|
作者：
Prokhorov, A. D. [1 ]
Krygin, I. N. [1 ]
Prokhorov, A. A. [1 ]
Chernush, L. F. [1 ]
Aleshkevich, P. [2 ]
Dyakonov, V. [1 ,2 ]
Szymczak, H. [2 ]
机构：
[1] NANU, AA Galkin Donetsk Physicotech Inst, UA-83114 Donetsk, Ukraine
[2] PAS, Inst Phys, PL-02668 Warsaw, Poland
来源：
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2009年 / 206卷 / 11期
关键词：
SUPERPOSITION MODEL; YTTRIUM; SPECTRA; BORATE; FIELD;
D O I：
10.1002/pssa.200925027
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The ground state of Gd3+ ions substituting for Y3+ in YAl3(BO3)(4) single crystal has been studied by EPR method. Spin Hamiltonian parameters and their signs for Gd3+ ion in trigonal symmetry (g(z) = 1.9893 +/- 0.0002, g(x) = g(y) = 1.9860 +/- 0.0002; b(2)(0) = 386.15 +/- 0.11; b(4)(0) = -12.65 +/- 0.07; b(6)(0) = 0.35 +/- 0.10) were determined. Structural phase transition manifested as a discontinuous change of splitting of spectrum was observed near 157 K. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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收藏
页码：2617 / 2621
页数：5
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