Synthesis of a Stable B2H5+ Analogue by Protonation of a Double Base-Stabilized Diborane(4)

被引：61

作者：

Ciobanu, Oxana ^{[1
]}

Kaifer, Elisabeth ^{[1
]}

Enders, Markus ^{[1
]}

Himmel, Hans-Joerg ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 30期

关键词：

boron; diborane(4); hydrides; main-group elements; protonation; STRUCTURAL-CHARACTERIZATION; INFRARED-SPECTRA; MATRIX-ISOLATION; MOLECULES; HYDRIDE;

D O I：

10.1002/anie.200901842

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polarity of H+ reversed: The synthesis of [B2H 3(hpp)2]+I-,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted into a hydride. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5538 / 5541

页数：4

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