Synthesis of a Stable B2H5+ Analogue by Protonation of a Double Base-Stabilized Diborane(4)

被引：61

作者：

Ciobanu, Oxana ^{[1
]}

Kaifer, Elisabeth ^{[1
]}

Enders, Markus ^{[1
]}

Himmel, Hans-Joerg ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 30期

关键词：

boron; diborane(4); hydrides; main-group elements; protonation; STRUCTURAL-CHARACTERIZATION; INFRARED-SPECTRA; MATRIX-ISOLATION; MOLECULES; HYDRIDE;

D O I：

10.1002/anie.200901842

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polarity of H+ reversed: The synthesis of [B2H 3(hpp)2]+I-,a dinuclear borohydride with terminal and bridging H atoms (see picture; B yellow, N blue, C gray, H white, I purple), is made possible with the ligand hexahydropyrimidopyrimidate (hpp). In the course of the reaction the proton is converted into a hydride. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5538 / 5541

页数：4

共 50 条

[1] Thermal Dehydrogenation of Base-Stabilized B2H5+ Complexes and Its Role in CH Borylation
Prokofjevs, Aleksandrs
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (45) : 13401 - 13405
[2] Synthesis and Characterization of a Doubly Base-Stabilized B3H6+ Analogue
Schulenberg, Nikola
Wadepohl, Hubert
Himmel, Hans-Joerg
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (44) : 10444 - 10447
[3] ONIUM IONS .37. HYDROGEN-DEUTERIUM EXCHANGE OF DIBORANE IN SUPERACID SOLUTION THROUGH DIBORANONIUM (B2H7+) AND DIBORANIUM (B2H5+) IONS
OLAH, GA
ANISZFELD, R
PRAKASH, GKS
WILLIAMS, RE
LAMMERTSMA, K
GUNER, OF
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) : 7885 - 7886
[4] The Doubly Base-Stabilized Diborane(4) [HB(μ-hpp)]2 (hpp=1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate): Synthesis by Catalytic Dehydrogenation and Reactions with S8 and Disulfides
Schulenberg, Nikola
Ciobanu, Oxana
Kaifer, Elisabeth
Wadepohl, Hubert
Himmel, Hans-Joerg
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (33) : 5201 - 5210
[5] SYNTHESIS, STRUCTURE AND DYNAMIC STUDIES ON BASE-STABILIZED SILYLENE COMPLEXES [(ETA(5)-C(5)ME(5))(PME(3))(2)RUSIX(2)(NCME)(+)]
GRUMBINE, SK
STRAUS, DA
TILLEY, TD
RHEINGOLD, AL
POLYHEDRON, 1995, 14 (01) : 127 - 148
[6] Base Stabilized σ-Borane Complex of Group 5 Metals: Synthesis and Structure of [(η5-C5Me5)Ta(H3BNC5H4) (C5H4NS)(η2-S2)]
Haridas, Anagha
Saha, Suvam
Bedajna, Shantabh
Ghosh, Sundargopal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (27)
[7] RUTHENIUM AND OSMIUM BRIDGED DIBORANE(6) DERIVATIVES [(MU-RU(CO)4)B2H5-], [(MU-OS(CO)4)B2H5-]
COFFY, TJ
SHORE, SG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 158 - INOR
[8] Hydroboride, X B(2)H(5)J - The Synthesis of B4H10
Stock, A
Pohland, E
BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1926, 59 : 2223 - 2226
[9] BISCYCLOPENTADIENYLZIRCONIUM(IV) HYDRIDOALUMOHYDRIDE, ITS REACTION WITH DIBORANE AND THE SYNTHESIS OF [(ETA-5-C5H5)2ZRIV(BH4)(H2AL(BH4)2)]
SASNOVSKAYA, VD
TITOV, LV
ROSOLOVSKII, VY
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1984, 33 (06): : 1297 - 1301
[10] TRANSITION-METAL-PROMOTED REACTIONS OF BORON HYDRIDES .7. PLATINUM(II) BROMIDE CATALYZED CAGE GROWTH AND DEHYDROCOUPLING REACTIONS OF DIBORANE WITH SMALL POLYHEDRAL CARBORANES AND BORANES - SYNTHESIS OF A NEW ARACHNO CARBORANE, 5,6-C2B6H12, AND THE DIBORANE-COUPLED COMPOUNDS 2-1',2'[1,6-C2B4H5][B2H5] AND 2-1',2'-[B5H8][B2H5]
CORCORAN, EW
SNEDDON, LG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) : 7446 - 7450

← 1 2 3 4 5 →