Rapid degradation of malachite green by CoFe2O4-SiC foam under microwave radiation

被引:14
|
作者
Mao, Yanpeng [1 ]
Yang, Shanxiu [1 ]
Xue, Chao [1 ]
Zhang, Miaomiao [1 ]
Wang, Wenlong [1 ]
Song, Zhanlong [1 ]
Zhao, Xiqiang [1 ]
Sun, Jing [1 ]
机构
[1] Shandong Univ, Sch Energy & Power Engn, Natl Engn Lab Coal Fired Pollutants Emiss Reduct, Jinan 250100, Shandong, Peoples R China
来源
ROYAL SOCIETY OPEN SCIENCE | 2018年 / 5卷 / 06期
基金
中国国家自然科学基金;
关键词
microwave; CoFe2O4-SiC foam; organics; degradation; continuous treatment; FENTON-LIKE PROCESS; AQUEOUS-SOLUTION; ACTIVATED CARBON; LEUCOMALACHITE GREEN; CATALYTIC-ACTIVITY; P-NITROPHENOL; OXIDATION; REMOVAL; IRRADIATION; COMPOSITES;
D O I
10.1098/rsos.180085
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
This study demonstrated rapid degradation of malachite green (MG) by a microwave (MW)-induced enhanced catalytic process with CoFe2O4-SiC foam. The catalyst was synthesized from CoFe2O4 particles and SiC foam by the hydrothermal method. X-ray diffraction and scanning electron microscopy techniques were used to confirm that CoFe2O4 particles were settled on the surface of SiC foam. In this experiment, a novel fixed-bed reactor was set up with this catalyst for a continuous flow process in a MW oven. The different parameters that affect the MW-induced degradation rate of MG were explored. The MW irradiation leads to the effective catalytic degradation of MG, achieving 95.01% degradation within 5 min at pH 8.5. At the same time, the good stability and applicability of CoFe2O4-SiC foam for the degradation process were also discussed, as well as the underlying mechanism. In brief, these findings make the CoFe2O4-SiC foam an excellent catalyst that could be used in practical rapid degradation of MG.
引用
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页数:12
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