A test of optimal laser impulsion for controlling population within the Ns=1, Nr=5 polyad of 12C2H2

被引：4
|
作者：
Santos, L. [1 ]
Iacobellis, N. [1 ]
Herman, M. [1 ]
Perry, D. S. [2 ]
Desouter-Lecomte, M. [3 ,4 ]
Vaeck, N. [1 ]
机构：
[1] Univ Libre Bruxelles, Dept Chim, Lab Chim Quant & Photophys, Brussels, Belgium
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
[3] Univ Paris 11, Univ Paris Saclay, UMR8000, Chim Phys Lab, Orsay, France
[4] Univ Liege, Dept Chim, Liege, Belgium
来源：
MOLECULAR PHYSICS | 2015年 / 113卷 / 24期
关键词：
Optimal control; effective Hamiltonian; acetylene; polyad; ACETYLENE; SPECTROSCOPY; DYNAMICS; C2H2;
D O I：
10.1080/00268976.2015.1102980
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Optimal control theory has been employed to populate separately two dark states of the acetylene polyad, N-s = 1 and N-r= 5, by indirect coupling via the ground state. Relevant level energies and transition dipole moments are extracted from the experimental literature. The optimal pulses are rather simple. The evolution of the population is shown for the duration of the control process and also for the field-free evolution that follows the control. One of the dark states appears to be a potential target for realistic experimental investigation because the average population of the Rabi oscillation remains high and decoherence is expected to be weak.
引用
收藏
页码：4000 / 4006
页数：7
相关论文
共 50 条
  • [41] 固态配合物RE（C5H8NS2）3(C12H8N2)的光谱性质
    孟祥鑫
    陈三平
    焦宝娟
    高胜利
    中国稀土学报, 2004, (05) : 715 - 718
  • [42] A synthetic, structural, and 113Cd NMR study of cadmium complexes of 1,3-thiazolidine-2-thionate, including the structures of Cd(C3H4NS2)2, (Cd(C3H4NS2)2(C5H5N)3•C5H5N, and (Ph4P)2[I2Cd(μ-C3H4NS2)2CdI2]
    Craig, DC
    Dance, IG
    Dean, PAW
    Hook, JM
    Jenkins, HA
    Kirby, CW
    Scudder, ML
    Rajalingam, U
    CANADIAN JOURNAL OF CHEMISTRY, 2005, 83 (02) : 174 - 184
  • [43] ELECTRON-DIFFRACTION STUDY OF STRUCTURE OF MOLECULES C2H5PC12 AND (C2H5)2PC1
    NAUMOV, VA
    TUZOVA, LL
    ZARIPOV, NM
    JOURNAL OF STRUCTURAL CHEMISTRY, 1977, 18 (01) : 54 - 59
  • [44] Self-collisional broadening and shift coefficients of lines in the v4 + v5 band of 12C2H2 from 173.2 to 298.2 K by diode-laser spectroscopy
    Dhyne, Miguel
    Joubert, Pierre
    Populaire, Jean-Claude
    Lepere, Muriel
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2011, 112 (06): : 969 - 979
  • [45] The Q -branch of v1 + v3+3 v4 band of 12C2H2 located at 8330 cm-1
    Jacquemart, D.
    Lyulin, O. M.
    Solodov, A. M.
    Petrova, T. M.
    Solodov, A. . A. .
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2022, 288
  • [46] STRUCTURE OF IODOBIS(1-PYRROLIDINECARBODITHIOATO)ANTIMONY(III), [SBI(C5H8NS2)2]
    KELLO, E
    KETTMANN, V
    GARAJ, J
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1985, 41 (APR): : 520 - 522
  • [47] High-precision frequency measurements of the v1 + v3 combination band of 12C2H2 in the 1.5 μm region
    Edwards, CS
    Barwood, GP
    Margolis, HS
    Gill, P
    Rowley, WRC
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2005, 234 (01) : 143 - 148
  • [48] Kinetics of thermal decomposition of Nd[(C5H10NS2)3 (C12H8N2)] in non-isothermal conditions
    Jiao, BJ
    Chen, SP
    Hu, RZ
    Gao, SL
    JOURNAL OF RARE EARTHS, 2005, 23 : 82 - 85
  • [49] SPEEDS OF SOUND, EXCESS MOLAR VOLUMES, AND ISENTROPIC COMPRESSIBILITIES OF (XCH3COC2H5+(1-X)C7H16), (XCH3COC2H5+(1-X)C-C6H12), (XCH3COC2H5+(1-X)C-C6H11CH3), (XC2H5COC2H5+(1-X)C7H16), AND (XC2H5COC2H5+(1-X)C-C6H12) AT 298.15-K
    OHOMURO, K
    TAMURA, K
    MURAKAMI, S
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (02): : 163 - 169
  • [50] High resolution stimulated Raman spectroscopy from collisionally populated states after optical pumping: the 3222 and 2+24+524+5Q branches of 12C2H2 and the 3222Q branch of 12C2D2.
    Martinez, Raul Z.
    Bermejo, Dionisio
    Di Lonardo, Gianfranco
    Fusina, Luciano
    JOURNAL OF RAMAN SPECTROSCOPY, 2017, 48 (02) : 251 - 257
12345