UV/visible-light photodegradation of organic dyes over mesoporous titania prepared by using 2,4,5-triphenylimidazole as template

被引:7
|
作者
Tao, Jun [1 ,2 ]
Gong, Wenjuan [1 ]
Yan, Zhiying [1 ]
Duan, Deliang [1 ]
Zeng, Yanbo [1 ]
Wang, Jiaqiang [1 ]
机构
[1] Yunnan Univ, Univ Ctr Photocatalyt Treatment Pollutants Yunnan, Sch Chem Sci & Technol, Kunming 650091, Peoples R China
[2] Kunming Univ Sci & Technol, Sch Chem Engn, Kunming 650091, Peoples R China
基金
中国国家自然科学基金;
关键词
Mesoporous TiO2; Visible-light photocatalysis; UV light photocatalysis; 2,4,5-Triphenylimidazole; Dyes; ENHANCED PHOTOCATALYTIC ACTIVITY; NANOCRYSTALLINE TIO2; AMORPHOUS TITANIA; DEGRADATION; CRYSTALLINE; ANATASE; TRANSFORMATION; RUTILE; PHASE; SOL;
D O I
10.1016/j.mssp.2014.07.026
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this work, mesoporous TiO2 compose of anatase and brookite phases (M-TiO2) has been synthesized using 2,4,5-tiiphenylimidazole as template. The physical features of the as-prepared catalyst was measured by X-ray diffraction (XRD), low-temperature nitrogen adsorption/desorption, UV-visible diffuse reflectance spectrum, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The photocatalytic performance of the catalyst was evaluated in terms of the degradation of organic dyes, It is found that M-TiO2 exhibits reasonable activity under UV light and can significantly degrade methylthionine chloride, rhodamine B, gentian violet, safranine T, methyl violet and fuchsine basic under visible-light irradiation (lambda >= 420 nm). (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:452 / 460
页数:9
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