Complexation of the thallium cation with nonactin: an experimental and theoretical study

被引：20
|
作者：
Makrlik, Emanuel [1 ]
Toman, Petr [2 ]
Vanura, Petr [3 ]
机构：
[1] Czech Univ Life Sci, Fac Environm Sci, Prague, Czech Republic
[2] Acad Sci Czech Republ, Inst Macromol Chem, Prague, Czech Republic
[3] Inst Chem Technol, Dept Analyt Chem, CR-16628 Prague, Czech Republic
来源：
MONATSHEFTE FUR CHEMIE | 2014年 / 145卷 / 04期
关键词：
Antibiotics; Macrocycles; Complexation; DFT calculations; Structures; STOFFWECHSELPRODUKTE VON ACTINOMYCETEN; INDIVIDUAL EXTRACTION CONSTANTS; UBER DIE KONSTITUTION; ALKALI-METAL CATIONS; SOLVENT-EXTRACTION; HYDROGEN DICARBOLLYLCOBALTATE; UNIVALENT CATIONS; HYDRONIUM ION; UNEX PROCESS; NITROBENZENE;
D O I：
10.1007/s00706-014-1153-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From extraction experiments in the two-phase water/nitrobenzene system and gamma-activity measurements, the stability constant of the nonactin-Tl+ complex species dissolved in nitrobenzene saturated with water was determined. By using quantum-mechanical calculations, the most probable structure of this complex was predicted.
引用
收藏
页码：551 / 555
页数：5
相关论文
共 50 条
  • [21] Complexation of the thallium cation with dibenzo-30-crown-10: extraction and theoretical study
    Makrlik, Emanuel
    Toman, Petr
    Vanura, Petr
    MONATSHEFTE FUR CHEMIE, 2013, 144 (07): : 919 - 923
  • [22] Complexation of the potassium cation with enniatin B: an experimental and theoretical study
    Emanuel Makrlík
    Stanislav Böhm
    Petr Vaňura
    Monatshefte für Chemie - Chemical Monthly, 2016, 147 : 1687 - 1692
  • [23] Complexation of the thallium cation with dibenzo-30-crown-10: extraction and theoretical study
    Emanuel Makrlík
    Petr Toman
    Petr Vaňura
    Monatshefte für Chemie - Chemical Monthly, 2013, 144 : 919 - 923
  • [24] Experimental and theoretical study on cation-π interaction of the univalent thallium cation with [2.2.2]paracyclophane
    Makrlik, Emanuel
    Boehm, Stanislav
    Sykora, David
    Klepetarova, Blanka
    Vanura, Petr
    Polasek, Miroslav
    CHEMICAL PHYSICS LETTERS, 2015, 642 : 39 - 42
  • [25] Reaction of the thallium(I) cation with [2.2]paracyclophane: Experimental and theoretical study
    Vanura, Petr
    Sykora, David
    Uhlikova, Tereza
    INORGANICA CHIMICA ACTA, 2022, 543
  • [26] Complexation of the sodium cation with sodium ionophore III: Experimental and theoretical study
    Makrlik, Emanuel
    Kvicala, Jaroslav
    Vanura, Petr
    JOURNAL OF MOLECULAR STRUCTURE, 2014, 1067 : 216 - 219
  • [27] Complexation of the strontium cation with a macrocyclic lactam receptor: Experimental and theoretical study
    Makrlik, Emanuel
    Zalis, Stanislav
    Vanura, Petr
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 214 : 171 - 174
  • [28] Cation-π interaction of thallium (I) with [7]helicene: an experimental and theoretical study
    Vanura, Petr
    Sykora, David
    Bohm, Stanislav
    Uhlikova, Tereza
    MOLECULAR PHYSICS, 2022, 120 (11)
  • [29] Experimental and Theoretical Study of the Complexation of Cesium and Thallium Cations by a Water-Soluble Cryptophane
    Chapellet, Laure-Lise
    Dognon, Jean-Pierre
    Jean, Marion
    Vanthuyne, Nicolas
    Berthault, Patrick
    Buffeteau, Thierry
    Brotin, Thierry
    CHEMISTRYSELECT, 2017, 2 (19): : 5292 - 5300
  • [30] Experimental and theoretical study on complexation of the calcium cation with [Gly6]-antamanide
    Makrlik, Emanuel
    Bohm, Stanislav
    Vanura, Petr
    Ruzza, Paolo
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 242 : 423 - 427
12345