High selectivity of TaSiBEA zeolite catalysts in 1,3-butadiene production from ethanol and acetaldehyde mixture

被引：64
|
作者：
Kyriienko, Pavlo I. [1 ]
Larina, Olga V. [1 ]
Soloviev, Sergiy O. [1 ]
Orlyk, Svitlana M. [1 ]
Dzwigaj, Stanislaw [2 ,3 ]
机构：
[1] NAS Ukraine, LV Pisarzhevsky Inst Phys Chem, 31 Prosp Nauky, UA-03028 Kiev, Ukraine
[2] Univ Paris 06, Sorbonne Univ, UMR 7197, Lab React Surface, F-75005 Paris, France
[3] CNRS, UMR 7197, Lab React Surface, F-75005 Paris, France
来源：
CATALYSIS COMMUNICATIONS | 2016年 / 77卷
关键词：
Tantalum; BEA; Ethanol; 1,3-Butadiene; Catalysis; ONE-STEP; CONVERSION; BUTADIENE; SITES; FRAMEWORK; PYRROLE; FTIR; BETA;
D O I：
10.1016/j.catcom.2016.01.023
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
New tantalum-silica based zeolite catalysts (TaSiBEA) were applied in this work for 1,3-butadiene production from ethanol. Tantalum incorporation into vacant T-atom sites of the SiBEA zeolites framework as mononuclear Ta(V) allowed preparing highly selective catalysts for ethanol/acetaldehyde mixture conversion into 1,3-butadiene, with selectivity to 1,3-butadiene of 80-90% at total conversion of the mixture of 45-30%. Effect of Ta content on activity of TaSiBEA zeolite catalysts and the ethanol/acetaldehyde molar ratio in selective production of 1,3 butadiene were demonstrated. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：123 / 126
页数：4
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