Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

被引：56

作者：

Aricó, CS ^{[1
]}

Cox, LR ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 18期

关键词：

D O I：

10.1039/b409832c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.

引用

页码：2558 / 2562

页数：5

共 29 条

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ORGANIC LETTERS, 2005, 7 (09) : 1805 - 1808
[23] Experimental and theoretical study on the olefin metathesis of alkenyl Baylis-Hillman adducts using second-generation Grubbs catalyst
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[27] The first platinum(0)-catalyzed regio- and stereoselective thiosilylation of alkynes using disulfides and disilanes: A new strategy for introducing two different heteroatoms into carbon-carbon unsaturated bonds
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[28] Transfer-hydrogenation reactions of ketones/aldehydes in water using first generation ruthenium indenylidene olefin metathesis catalyst: One step towards sequential cross-metathesis/transfer hydrogenation reactions
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MOLECULAR CATALYSIS, 2020, 480
[29] The bis(trifluoroacetate) analogue of the first-generation Grubbs catalyst: Synthesis, X-ray structure, and metathesis activity of [Ru(CF3CO2) (η2-CF3CO2)(=CHPh)(PCy3)2]
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