Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst

被引：56
|
作者：
Aricó, CS [1 ]
Cox, LR [1 ]
机构：
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 18期
关键词：
D O I：
10.1039/b409832c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.
引用
收藏
页码：2558 / 2562
页数：5
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