Catalyzed reactions of enolates and cations:: A novel method for enolate alkylation

被引：0
|
作者：
Gansäuer, A [1 ]
Fielenbach, D [1 ]
Stock, C [1 ]
机构：
[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2002年 / 344卷 / 08期
关键词：
alkylation; boron; catalysis; copper; enolate;
D O I：
10.1002/1615-4169(200209)344:8<845::AID-ADSC845>3.0.CO;2-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The first tertiary alkylations, alkoxyalkylations, and aldehyde enolate allylations are described proceeding with low catalyst loading (0.1 mol % to 5 mol %). The reactions proceed in short times, can be performed without solvent and under ambient conditions.
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页码：845 / 848
页数：4
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