Catalyst and Additive-Free Selective Ring-Opening Selenocyanation of Heterocycles with Elemental Selenium and TMSCN

被引：16

作者：

Lu, Li-Guo ^{[1
]}

Bi, Kang ^{[1
]}

Huang, Xiao-Bo ^{[1
]}

Liu, Miao-Chang ^{[1
]}

Zhou, Yun-Bing ^{[1
]}

Wu, Hua-Yue ^{[1
]}

机构：

[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Ring-Opening; Selenocyanation; Heterocycles; Elemental Selenium; Radical; OXABICYCLIC COMPOUNDS; BETA-HYDROXY; AZIRIDINES; ORGANOSELENIUM; EPOXIDES; ALCOHOLS; HYDROGENATION; DISELENIDES; LIGATION; OXETANES;

D O I：

10.1002/adsc.202001423

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A catalyst and additive-free strategy for selective ring-opening selenocyanation of saturated heterocycles with elemental selenium and TMSCN is developed, affording a series of aliphatic selenocyanates and selenaheterocycles. In the case of unprotected unstrained N-heterocycles, the reactions offer ammonium selenonitriles that prove to be an efficient selenonitrile reagent.

引用

页码：1346 / 1351

页数：6

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