Synthesis and structure of new BiMn2MO6 compounds where M=P, As, or V

被引：31
|
作者：
Xun, X [1 ]
Uma, S [1 ]
Yokochi, A [1 ]
Sleight, AW [1 ]
机构：
[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 167卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1006/jssc.2002.9654
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new compounds BiMn2PO6, BiMn2AsO6, and BiMn2 VO6 have been prepared and shown to be structurally related to several other BiA(2)MO(6) compounds. The structure of BiMn2PO6 was refined from neutron powder diffraction data in space group Pnma with a = 12.04 Angstrom, b = 5.37 Angstrom, c = 8.13 Angstrom, and Z = 4. It contains (BiO2)(1-) chains and (PO4)(3-) tetrahedra. The observed fivefold coordination for the Mn2+ cations is unusual for Mn in this oxidation state. (C) 2002 Elsevier Science (USA).
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页码：245 / 248
页数：4
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