Synthesis and structure of new BiMn2MO6 compounds where M=P, As, or V

被引：31
|
作者：
Xun, X [1 ]
Uma, S [1 ]
Yokochi, A [1 ]
Sleight, AW [1 ]
机构：
[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 167卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1006/jssc.2002.9654
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new compounds BiMn2PO6, BiMn2AsO6, and BiMn2 VO6 have been prepared and shown to be structurally related to several other BiA(2)MO(6) compounds. The structure of BiMn2PO6 was refined from neutron powder diffraction data in space group Pnma with a = 12.04 Angstrom, b = 5.37 Angstrom, c = 8.13 Angstrom, and Z = 4. It contains (BiO2)(1-) chains and (PO4)(3-) tetrahedra. The observed fivefold coordination for the Mn2+ cations is unusual for Mn in this oxidation state. (C) 2002 Elsevier Science (USA).
引用
收藏
页码：245 / 248
页数：4
相关论文
共 50 条
  • [1] Synthesis and determination of the crystal structure of hydrides of Er(M, V)2, where M = Fe or Co, compounds
    M'yakush, O
    Verbovyts'kyi, Y
    Saldan, I
    Koval'chuk, I
    Zavalii, I
    Kotur, B
    MATERIALS SCIENCE, 2004, 40 (06) : 781 - 786
  • [2] Synthesis and Determination of the Crystal Structure of Hydrides of Er(M, V)2, where M = Fe or Co, Compounds
    O. M’yakush
    Yu. Verbovyts’kyi
    I. Saldan
    I. Koval’chuk
    I. Zavalii
    B. Kotur
    Materials Science, 2004, 40 : 781 - 786
  • [3] Electron structure and photocatalytic activity of new compounds CsMxW2-xO6 (M = Sn, V and Mo, x=0-0.5) with β-pyrochlore structure
    Fukina, Diana G.
    Ganov, Alexander S.
    Boryakov, Aleksey V.
    Koroleva, Alexandra V.
    Zhizhin, Evgeny V.
    Titaev, Dmitry N.
    Shilova, Elena V.
    Suleimanov, Evgeny V.
    JOURNAL OF SOLID STATE CHEMISTRY, 2024, 337
  • [4] SYNTHESIS OF MOLYBDENUM(V) AND RHENIUM(V) CHLORIDE COMPLEXES WITH 18-CROWN-6 - CRYSTALLINE AND MOLECULAR-STRUCTURE OF PRODUCTS OF HYDROLYSIS OF MOCL3(18-CROWN-6).H2O COMPOUNDS WHERE (M=MO-V, RE-V)
    SERGIENKO, VS
    MINACHEVA, LK
    ASHUROVA, NK
    PORAIKOSHITS, MA
    YAKUBOV, KG
    SAKHAROVA, VG
    ZHURNAL NEORGANICHESKOI KHIMII, 1991, 36 (02): : 381 - 392
  • [5] Hydrothermal Synthesis and Characterization of Two New Phosphatomolybdates(V) Containing Sandwich-Shaped [M(Mo6P4)2] Clusters (M = Co, Ni)
    Bi-Zhou Lin
    Guo-Hua Han
    Bai-Huan Xu
    Ling Bai
    Yun-Long Feng
    Hong Su
    Journal of Cluster Science, 2008, 19 : 379 - 390
  • [6] Hydrothermal synthesis and characterization of two new phosphatomolybdates(V) containing sandwich-shaped [M(Mo6P4)2] clusters (M = Co, Ni)
    Lin, Bi-Zhou
    Han, Guo-Hua
    Xu, Bai-Huan
    Bai, Ling
    Feng, Yun-Long
    Su, Hong
    JOURNAL OF CLUSTER SCIENCE, 2008, 19 (02) : 379 - 390
  • [7] REACTIONS OF M2(OR)6 COMPOUNDS (M M, M = MO, W) WITH THIOKETONES
    BUDZICHOWSKI, T
    CHISHOLM, MH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 155 - INOR
  • [8] MOLECULAR ROUTES FOR THE SYNTHESIS OF METAL CARBIDES, NITRIDES, AND OXIDES .1. STUDIES OF THE THERMAL-DECOMPOSITION OF M(2)(OR)(6) AND M(2)(CH(2)PH)(2)(OR)(4) COMPOUNDS WHERE M=MO AND W
    BAXTER, DV
    CHISHOLM, MH
    DISTASI, VF
    HAUBRICH, ST
    CHEMISTRY OF MATERIALS, 1995, 7 (01) : 84 - 92
  • [9] SYNTHESIS, CRYSTAL-STRUCTURE AND SPECTROSCOPIC STUDIES OF NEW CHARGE-TRANSFER COMPOUNDS DERIVED FROM THE ORGANIC DONOR MOLECULE TETRATHIAFULVALENE, TTF, AND INORGANIC POLYOXOANIONS [M6O19]2-, WHERE M = MO, W
    ATTANASIO, D
    BELLITTO, C
    BONAMICO, M
    FARES, V
    IMPERATORI, P
    GAZZETTA CHIMICA ITALIANA, 1991, 121 (03): : 155 - 162
  • [10] MO,50NBSE2 PHASES (WHERE M= TI, V, CR) AND STRUCTURE OF CRO,50NBSE2
    MEERSCHAUT, A
    ROUXEL, J
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1973, 277 (03): : 163 - 166
12345