Chloroperoxidase-catalyzed oxidation of methionine derivatives

被引：16

作者：

Holland, HL ^{[1
]}

Brown, FM ^{[1
]}

Lozada, D ^{[1
]}

Mayne, B ^{[1
]}

Szerminski, WR ^{[1
]}

van Vliet, AJ ^{[1
]}

机构：

[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2002年 / 80卷 / 06期

关键词：

amino acid oxidation; biocatalysis; biotransformation; chloroperoxidase; enzyme catalysis; lipase; sulfoxidation;

D O I：

10.1139/V02-025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of N-methoxycarbonyl C-carboxylate ester derivatives of L- and D-methionine and L-ethionine by chloroperoxidase-hydrogen peroxide resulted in oxidation at sulfur to produce the (R-S) sulfoxide in moderate to high diastereomeric excess. The (R-S) sulfoxide of methionine was also obtained in moderate to high diastereomeric excess from (+/-)(SO)-N-methoxycarbonyl-L-methionine methyl ester sulfoxide by ester hydrolysis using alpha-chymotrypsin, Aspergillus sp. protease or subtilisin Carlsberg.

引用

页码：633 / 639

页数：7

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