Crystal growth and X-ray structure determination of Rb3Bi2I9

被引：25

作者：

Sidey, VI ^{[1
]}

Voroshilov, YV ^{[1
]}

Kun, SV ^{[1
]}

Peresh, EY ^{[1
]}

机构：

[1] Uzhgorod State Univ, Dept Chem, UA-294000 Uzhgorod, Ukraine

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2000年 / 296卷 / 1-2期

关键词：

ternary halides; preparation; crystal growth; crystal structure;

D O I：

10.1016/S0925-8388(99)00481-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The compound Rb3Bi2I9 was synthesized by melting a stoichiometric mixture of RbI and BiI3 and annealing for 1 month some degrees below the melting temperature of 785+/-5K; a large single crystal of the title compound has been grown from the melt by directional solidification using the vertical Bridgman-Stockbarger technique. X-ray structure determination of the compound involved single-crystal diffractometry, direct and Patterson methods and least-squares refinement. Rb3Bi2I9 exhibits a new type of crystal structure, crystallizing in the monoclinic space group Pc with unit-cell parameters a=14.690(4), b=8.195(2), c=25.645(6) Angstrom, beta=125.39(2)degrees, V=2517(2) Angstrom(3), Z=4. The unit-cell of Rb3Bi2I9 has six pseudohexagonal RbI3 layers which are stacked along the direction near to the normal of the XY plane. Each BiI3 octahedron shares three corners with three other octahedra to form parallel Bi2I9 corrugated layers intersecting Z axis of the structure at an angle near 120 degrees. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

引用

页码：53 / 58

页数：6

共 50 条

[21] DETERMINATION OF RB AND CS BY X-RAY FLUORESCENCE
VINDEIS, AF
[J]. SPECTROCHIMICA ACTA, 1957, 9 (04): : 361 - 361
[22] X-ray crystal structure of Δ9-THC-tosylate
Gul, W.
Carvalho, P.
Slade, D.
Avery, M.
Duchek, J. R.
Bab, D. W.
Kimmich, D. J.
ElSohly, M. A.
[J]. PLANTA MEDICA, 2008, 74 (03) : 329 - 329
[23] Composition Engineering Growth of Cs3Bi2I9 Single Crystals with Low Defect Density for X-ray Detectors
Li, Anfeng
Yang, Manman
Tang, Peng
Hao, Xia
Wu, Lili
Tian, Wenbo
Yang, Dingyu
Zhang, Jingquan
[J]. ACS APPLIED MATERIALS & INTERFACES, 2023, 15 (19) : 23390 - 23401
[24] THE REVISED STRUCTURE OF PSEUDOANISATIN BY X-RAY CRYSTAL-STRUCTURE DETERMINATION
KOUNO, I
IRIE, H
KAWANO, N
KATSUBE, Y
[J]. TETRAHEDRON LETTERS, 1983, 24 (08) : 771 - 772
[25] Crystal structure determination of Ag2Ga by single crystal X-ray diffraction
Gunnæs, AE
Olsen, A
Zagierski, PT
Klewe, B
Karlsen, OB
Aasen, A
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1998, 213 (12): : 639 - 644
[26] Synthesis and X-ray crystal structure of [Cu(I)N(R2PS)2]3
Birdsall, DJ
Slawin, AMZ
Woollins, JD
[J]. INORGANIC CHEMISTRY, 1999, 38 (18) : 4152 - +
[27] DETERMINATION OF CRYSTAL STRUCTURE OF ORGANIC COMPOUNDS BY X-RAY DIFFRACTION
HARKER, D
[J]. PHYSICAL METHODS OF ORGANIC CHEMISTRY, 1954, 1 (03): : 2423 - 2450
[28] Direct determination of crystal structure from X-ray data
Avrami, M
[J]. PHYSICAL REVIEW, 1938, 54 (04): : 300 - 303
[29] TWINNING BY MEROHEDRY AND X-RAY CRYSTAL-STRUCTURE DETERMINATION
CATTI, M
FERRARIS, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (JAN1): : 163 - 165
[30] X-RAY DIFFRACTION DETERMINATION OF CRYSTAL + MOLECULAR STRUCTURE OF PENTAPHENYLANTIMONY
WHEATLEY, PJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (OCT): : 3718 - &

← 1 2 3 4 5 →