Volumetric, rheological, and optical properties of hydroxylamine hydrochloride aqueous solutions containing NaCl, KCl, and NH4Cl at 30A°C

被引:0
|
作者
Deosarkar, S. D. [1 ]
Puyad, A. L. [1 ]
Shaikh, U. B. [1 ]
Solanke, S. S. [1 ]
机构
[1] Swami Ramanand Teerth Marathwada Univ, Sch Chem Sci, Nanded 431606, MS, India
关键词
hydroxylamine hydrochloride; molecular interactions; viscosity coefficients; VISCOSITY B-COEFFICIENTS; ULTRASONIC VELOCITY; WATER; MIXTURES; DENSITY; ELECTROLYTES; ACETONITRILE; BEHAVIOR; SOLVENT; ACETATE;
D O I
10.1134/S0036024414040074
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities, viscosities, and refractive indices of aqueous solutions of hydroxylamine hydrochloride containing 0.05, 0.10, and 0.15 mol/dm(3) NaCl, KCl, and NH4Cl were measured at different concentrations of hydroxylamine hydrochloride at 30A degrees C. Viscosity coefficients A and B representing ion-ion and ion-solvent interactions were determined from Jones-Dole equation. Experimental properties and viscosity coefficients have been interpreted in terms of ion-ion and ion-solvent interactions. Ion-solvent interactions were found to be dominating over the ion-ion interactions in studied systems.
引用
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页码:596 / 600
页数:5
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