Synthesis and fluorescent properties of thiacalix[4]arenes containing terpyridyl fragments at the lower rim

被引：9
|
作者：
Muravev, A. A. [1 ]
Burilov, V. A. [2 ]
Solov'eva, S. E. [1 ]
Strel'nik, A. G. [1 ]
Latypov, Sh. K. [1 ]
Bazanova, O. B. [1 ]
Sharafutdinova, D. R. [1 ]
Antipin, I. S. [1 ,2 ]
Konovalov, A. I. [1 ]
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
[2] Kazan Volga Reg Fed Univ, Kazan 420008, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2014年 / 63卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
thiacalix[4]arenes; terpyridines; lanthanides; fluorescence; metal-organic net-works; nanoparticles; SILVER COORDINATION NETWORKS; MOLECULAR TECTONICS; COMPLEXATION PROPERTIES; PLATINUM COMPLEXES; THIACALIXARENES; BIOMOLECULES; REACTIVITY; PARAMETERS; SYSTEMS; PYRIDYL;
D O I：
10.1007/s11172-014-0416-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New thiacalix[4]arenes tetrasubstituted by terpyridyl fragments at the lower rims in the 1,3-alternate stereoisomeric form were synthesized. The molecules interact with Eu-III and Tb-III in the DMF solution to form highly luminescent nanoscale (21-26 nm) metal-organic structures with the 2: 1 metal-to-ligand stoichiometry and a narrow particle size distribution.
引用
收藏
页码：214 / 222
页数：9
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