Synthesis and fluorescent properties of thiacalix[4]arenes containing terpyridyl fragments at the lower rim

被引：9

作者：

Muravev, A. A. ^{[1
]}

Burilov, V. A. ^{[2
]}

Solov'eva, S. E. ^{[1
]}

Strel'nik, A. G. ^{[1
]}

Latypov, Sh. K. ^{[1
]}

Bazanova, O. B. ^{[1
]}

Sharafutdinova, D. R. ^{[1
]}

Antipin, I. S. ^{[1
,2
]}

Konovalov, A. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia

[2] Kazan Volga Reg Fed Univ, Kazan 420008, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2014年 / 63卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

thiacalix[4]arenes; terpyridines; lanthanides; fluorescence; metal-organic net-works; nanoparticles; SILVER COORDINATION NETWORKS; MOLECULAR TECTONICS; COMPLEXATION PROPERTIES; PLATINUM COMPLEXES; THIACALIXARENES; BIOMOLECULES; REACTIVITY; PARAMETERS; SYSTEMS; PYRIDYL;

D O I：

10.1007/s11172-014-0416-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New thiacalix[4]arenes tetrasubstituted by terpyridyl fragments at the lower rims in the 1,3-alternate stereoisomeric form were synthesized. The molecules interact with Eu-III and Tb-III in the DMF solution to form highly luminescent nanoscale (21-26 nm) metal-organic structures with the 2: 1 metal-to-ligand stoichiometry and a narrow particle size distribution.

引用

页码：214 / 222

页数：9

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