In order to confirm the similar behavior of Eu and Am in heterogeneous geological materials, we carried out the batch experiments for determining the sorption property of radionuclides, Eu-152 and Am-241. We used four different types of core rocks including biotite banded gneiss, biotite gneiss, metabasite and andestic tuff, and selected two samples per each lithology, one of which is fracture-bearing and another is fracture-free. Except for metabasites, rock samples of each type are similar in their compositions. We calculated sorption ratios of two radionuclides from the experimental results. Biotite gneiss and tuff had similar sorption trends for Eu-152 and Am-241 regardless of the existence of fractures, whereas two metabasite samples showed very different sorption properties. Such difference in the sorption trends revealed a close relationship with chemical compositions of the host rocks. Nevertheless, Eu-152 and Am-241 showed similar adsorption trends for all the samples with variable contact times regardless of petrography and pH variations, and particularly, the sorption trends of Eu-152 and Am-241 in the metabasites were similar. This observation suggests that En and Am have similar sorption properties on geological materials. Therefore, Eu can be used as a useful analogue of Am in all kinds of geological environments regardless of variations in lithology and pH of groundwater. In addition, sorption ratios of (152)En and Am-241 are correlated with the contents of P2O5 and TiO2, suggesting that the chemical components such as P2O5 and TiO2 might be important for deciphering the interaction between the radionuclide and groundwater.
