Determination of chemical kinetic properties of heterogeneous catalysts

被引：18
|
作者：
Katsanos, NA [1 ]
机构：
[1] Univ Patras, Dept Chem, GR-26504 Patras, Greece
来源：
JOURNAL OF CHROMATOGRAPHY A | 2004年 / 1037卷 / 1-2期
关键词：
reviews; kinetic studies; catalysts; time-resolved chromatography; inverse gas chromatography; reversed-flow gas chromatography; lateral interactions; surface diffusion; adsorption rates; surface energy;
D O I：
10.1016/j.chroma.2003.11.051
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
The importance of cooperation of heterogeneous catalysis with surface science is stressed for simultaneous adsorptive and catalytic measurements. Inverse gas chromatography and reversed-flow gas chromatography offer a suitable research ground for such collaboration. After a short introduction, adsorption physicochemical quantities of heterogeneous catalysts with typical recent results, chemical kinetic properties and surface energy of catalysts are described, stressing the important aspect of time-resolved chromatography, due to the heterogeneity of the solid surface of catalysts. Adsorption energies, local monolayer capacities, local isotherms and energy distribution functions are extensively described. Also, lateral molecular interactions, surface diffusion and adsorption rates on heterogeneous catalysts are described. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：125 / 145
页数：21
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