Indium trichloride catalyzed chemoselective conversion of aldehydes to gem-diacetates

被引：37

作者：

Yadav, JS ^{[1
]}

Reddy, BVS ^{[1
]}

Srinivas, C ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 14期

关键词：

D O I：

10.1081/SCC-120005425

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aldehydes are chemoselectively converted into the corresponding gem-diacetates at ambient temperature in high to quantitative yields using a catalytic amount of indium(III) chloride. The deprotection of the resulting gem-diacetates is achieved using the same catalyst in the presence of water.

引用

页码：2169 / 2174

页数：6

共 50 条

[1] Indium trichloride catalyzed chemoselective conversion of aldehydes to gem-diacetates
Yadav, JS
Reddy, BVS
Srinivas, C
SYNTHETIC COMMUNICATIONS, 2002, 32 (08) : 1175 - 1180
[2] LiBF4-mediated conversion of aldehydes to gem-diacetates
Yadav, JS
Reddy, BVS
Venugopal, C
Ramalingam, T
SYNLETT, 2002, (04) : 604 - 606
[3] Indium(III) chloride catalyzed allylation of gem-diacetates:: A facile synthesis of homoallyl acetates
Yadav, JS
Reddy, BVS
Madhuri, C
Sabitha, G
CHEMISTRY LETTERS, 2001, (01) : 18 - 19
[4] An Improved Method for the Synthesis of Allylic gem-Diacetates from α,β-Unsaturated Aldehydes Catalyzed by Lithium Tetrafluoroborate
Ono, Fumiaki
Nishioka, Kuniaki
Itami, Shirou
Takenaka, Hirotaka
Sato, Tsuneo
CHEMISTRY LETTERS, 2008, 37 (12) : 1248 - 1249
[5] A mild and efficient cleavage of gem-diacetates to aldehydes by CBr4
Ramalingam, T
Srinivas, R
Reddy, BVS
Yadav, JS
SYNTHETIC COMMUNICATIONS, 2001, 31 (07) : 1091 - 1095
[6] Mild and efficient conversion of aldehydes to gem-diacetates using 2nd generation ionic liquids
Yadav, J. S.
Reddy, B. V. S.
Sreedhar, P.
Kondaji, G.
Nagaiah, K.
CATALYSIS COMMUNICATIONS, 2008, 9 (05) : 590 - 593
[7] Cellulose Sulfuric Acid-Mediated Conversion of Aldehydes to gem-Diacetates under Solvent-Free Conditions
Fallah-Mehrjardi, Mehdi
Ghanemi, Kamal
JORDAN JOURNAL OF CHEMISTRY, 2013, 8 (04) : 247 - 252
[8] Indium-mediated allylation of gem-diacetates to homoallylic acetates in aqueous media
Yadav, JS
Reddy, BVS
Reddy, GSKK
TETRAHEDRON LETTERS, 2000, 41 (15) : 2695 - 2697
[9] Chemoselective titanium (IV)-catalyzed conversion of aldehydes to 1,1-diacetates
Jung, Misuk
Yoon, Jieun
Ryu, Jae-Sang
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
[10] Gallium(III) chloride: an efficient catalyst for facile preparation of gem-diacetates from aldehydes
Kumar, Sanjay
Saini, Anil
Sandhu, Jagir S.
ARKIVOC, 2007, : 27 - 33

← 1 2 3 4 5 →