Indium(III) chloride catalyzed allylation of gem-diacetates:: A facile synthesis of homoallyl acetates

被引:18
|
作者
Yadav, JS [1 ]
Reddy, BVS [1 ]
Madhuri, C [1 ]
Sabitha, G [1 ]
机构
[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India
关键词
D O I
10.1246/cl.2001.18
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Indium(III) chloride is found to catalyze efficiently the allylation of gem-diacetates with allyltrimethylsilane at room temperature to afford the corresponding homoallylic acetates in high yields with good regioselectivity.
引用
收藏
页码:18 / 19
页数:2
相关论文
共 50 条
  • [1] Scandium triflate catalyzed allylation of acetals and gem-diacetates:: A facile synthesis of homoallyl ethers and acetates
    Yadav, JS
    Reddy, BVS
    Srihari, P
    SYNLETT, 2001, (05) : 673 - 675
  • [2] Indium-mediated allylation of gem-diacetates to homoallylic acetates in aqueous media
    Yadav, JS
    Reddy, BVS
    Reddy, GSKK
    TETRAHEDRON LETTERS, 2000, 41 (15) : 2695 - 2697
  • [3] Indium trichloride catalyzed chemoselective conversion of aldehydes to gem-diacetates
    Yadav, JS
    Reddy, BVS
    Srinivas, C
    SYNTHETIC COMMUNICATIONS, 2002, 32 (08) : 1175 - 1180
  • [4] Indium trichloride catalyzed chemoselective conversion of aldehydes to gem-diacetates
    Yadav, JS
    Reddy, BVS
    Srinivas, C
    SYNTHETIC COMMUNICATIONS, 2002, 32 (14) : 2169 - 2174
  • [5] Gallium(III) chloride: an efficient catalyst for facile preparation of gem-diacetates from aldehydes
    Kumar, Sanjay
    Saini, Anil
    Sandhu, Jagir S.
    ARKIVOC, 2007, : 27 - 33
  • [6] Mono-Allylation of Gem-Diacetates with Allylsamarium Bromide
    Xiao Xia WANG1
    Chinese Chemical Letters, 2001, (11) : 943 - 944
  • [7] Mono-allylation of gem-diacetates with allylsamarium bromide
    Wang, XX
    Zhang, YM
    CHINESE CHEMICAL LETTERS, 2001, 12 (11) : 943 - 944
  • [8] Synthesis of chromane derivatives by palladium-catalyzed intramolecular allylation of aldehydes with allylic acetates or chlorides using indium and indium(III) chloride
    Nguyen, VC
    Kim, YT
    Yu, YK
    Kang, HY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (05): : 711 - 712
  • [9] An Improved Method for the Synthesis of Allylic gem-Diacetates from α,β-Unsaturated Aldehydes Catalyzed by Lithium Tetrafluoroborate
    Ono, Fumiaki
    Nishioka, Kuniaki
    Itami, Shirou
    Takenaka, Hirotaka
    Sato, Tsuneo
    CHEMISTRY LETTERS, 2008, 37 (12) : 1248 - 1249
  • [10] Synthesis of homoallyl ethers via iron(III) tosylate catalyzed allylation of acetals
    Mohan, Ram S.
    Anderson, Erin D.
    Palma, Ann C.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233