Equilibrium and kinetic modeling of high-pressure pyrolysis and oxidation of hydrocarbons

被引：4
|
作者：
Dvornikov, NA [1 ]
机构：
[1] Russian Acad Sci, Inst Thermal Phys, Siberian Div, Novosibirsk 630090, Russia
来源：
COMBUSTION EXPLOSION AND SHOCK WAVES | 1999年 / 35卷 / 03期
关键词：
D O I：
10.1007/BF02674443
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The pyrolysis and incomplete oxidation of hydrocarbons in the presence of water at high pressures is modeled numerically. The calculations show that the nonidealness of the gas can have a significant effect on the composition and temperature of the reaction products. The results of equilibrium and global kinetics calculations are in better agreement with one another, but a model with detailed kinetics fits the experimental data better.
引用
收藏
页码：230 / 238
页数：9
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