The oxidation of fullerene [C70] with various oxidants by ultrasonication

被引:9
|
作者
Ko, WB [1 ]
Baek, KN [1 ]
机构
[1] Sahmyook Univ, Dept Chem, Seoul 139742, South Korea
关键词
oxidation of fullerene [C-70; various oxidants; ultrasonication; FAB-MS;
D O I
10.1016/S0041-624X(02)00377-3
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
The reaction of C-70 by ultrasonication with various oxidants such as 3-chloroperoxy benzoic acid (Fluka 99%), 4-methyl morpholine N-oxide (Aldrich 97%), chromium (VI) oxide (Aldrich 99.9%), and oxone(R) monopersulfate compound, at room temperature causes the oxidation of fullerene [CM70(O)(n)] (n = 1-2 or n = 1). The FAB-MS, UV-visible, FT-IR spectra, and HPLC analysis confirmed that products of fullerene oxidation are [C-70(O)(n)] (n = 1-2 or n = 1). (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:729 / 733
页数:5
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