Thermodynamic properties of liquid Al-Sn-Zn alloys: A possible new lead-free solder material

被引:24
|
作者
Knott, S [1 ]
Mikula, A [1 ]
机构
[1] Univ Vienna, Inst Anorgan Chem, A-1090 Vienna, Austria
关键词
aluminum-tin-zinc ternary system; thermodynamic properties; lead-free solder materials; electromotive force measurements;
D O I
10.2320/matertrans.43.1868
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Because of its potential to be used as a lead free solder material the thermodynamic properties of the liquid Al-Sn-Zn system were investigated. Using an appropriate galvanic cell, the partial free energies of Al were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 30 alloys. Their composition was situated on three cross-sections with constant ratios of Sn:Zn 2: 1, 1:1 and 1:2. The integral Gibbs energy and the integral enthalpy for the ternary system at 973 K were calculated by Gibbs-Duhem integration.
引用
收藏
页码:1868 / 1872
页数:5
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