Transport property of an organic conductor α-(BEDT-TTF)2I3 under high pressure -: Discovery of a novel type of conductor

被引:146
|
作者
Tajima, N
Tamura, M
Nishio, Y
Kajita, K
Iye, Y
机构
[1] Toho Univ, Dept Phys, Funabashi, Chiba 2748510, Japan
[2] Univ Tokyo, Inst Solid State Phys, Minato Ku, Tokyo 1068666, Japan
关键词
alpha-(BEDT-TTF)(2)I-3; organic conductor; semimetal; narrow gap semiconductor; high pressure; conductivity; Hall effect; carrier density; mobility;
D O I
10.1143/JPSJ.69.543
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We have found quite a new type of transport phenomenon in an organic crystal alpha-(BEDT-TTF)(2)I-3 under high pressure. Essentially, it is a semimetal or a narrow gap semiconductor. But, the transport property is peculiar. The conductivity of this the carrier (hole) density and mobility change by a about 6 orders of magnitude. They change in a manner so that the effects just cancel out giving rise to the temperature independent conductivity. At low temperatures, the system is in a state with high mobility (3 x 10(5) cm(2)/V.sec) and low carrier density (5 x 10(15) cm(-3)). This state has been found to be very sensitive to magnetic field. We propose a mechanism for the extremely strong temperature dependence of the carrier density. It is based on the band structure and takes the thermal effect into consideration.
引用
收藏
页码:543 / 551
页数:9
相关论文
共 50 条
  • [41] Electronic properties close to Dirac cone in two-dimensional organic conductor α-(BEDT-TTF)2I3
    Katayama, S.
    Kobayashi, A.
    Suzumura, Y.
    EUROPEAN PHYSICAL JOURNAL B, 2009, 67 (02): : 139 - 148
  • [42] MICROWAVE CONDUCTIVITY IN THE PURE AND IODINE-DOPED ORGANIC CONDUCTOR ALPHA-(BEDT-TTF)2I3
    KREMER, W
    HELBERG, HW
    GOGU, E
    SCHWEITZER, D
    KELLER, HJ
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1987, 91 (09): : 896 - 899
  • [43] Correlation Effects on Charge Order and Zero-Gap State in the Organic Conductor α-(BEDT-TTF)2I3
    Tanaka, Yasuhiro
    Ogata, Masao
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2016, 85 (10)
  • [44] Electronic properties close to Dirac cone in two-dimensional organic conductor α-(BEDT-TTF)2I3
    S. Katayama
    A. Kobayashi
    Y. Suzumura
    The European Physical Journal B, 2009, 67 : 139 - 148
  • [45] SdH experiments on the organic superconductor κ-(BEDT-TTF)2I3 under hydrostatic pressure
    Nothardt, A
    Balthes, E
    Schmidt, W
    Schweitzer, D
    Kartsovnik, MV
    Sheikin, I
    JOURNAL DE PHYSIQUE IV, 2004, 114 : 351 - 353
  • [46] NMR INVESTIGATIONS OF THE ORGANIC METALS AND SUPERCONDUCTORS ALPHA-(BEDT-TTF)2I3, BETA-(BEDT-TTF)2I3 AND ALPHA-T-(BEDT-TTF)2I3
    HENNIG, I
    HAEBERLEN, U
    HEINEN, I
    SCHWEITZER, D
    KELLER, HJ
    PHYSICA C, 1988, 153 (01): : 493 - 494
  • [47] Hall effect and orbital diamagnetism in zerogap state of molecular conductor α-(BEDT-TTF)2I3
    Kobayashi, Akito
    Suzumura, Yoshikazu
    Fukuyama, Hidetoshi
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2008, 77 (06)
  • [48] The electronic state of α-(BEDT-TTF)2I3 under hydrostatic pressure
    Kubo, Y
    Takano, Y
    Hiraki, K
    Takahashi, T
    Yamamoto, HM
    Nakamura, T
    SYNTHETIC METALS, 2003, 133 : 307 - 308
  • [49] INVESTIGATIONS OF THE TRANSPORT-PROPERTIES OF THE ORGANIC SUPERCONDUCTORS BETA-(BEDT-TTF)2I3 AND BETA-T-(BEDT-TTF)2I3
    KAHLICH, S
    SCHWELTZER, D
    KELLER, HJ
    SOLID STATE COMMUNICATIONS, 1990, 76 (07) : 933 - 936
  • [50] Crystal and Electronic Structures of the Quasi-Two-Dimensional Organic Conductor α-(BEDT-TTF)2I3 and Its Selenium Analogue α-(BEDT-TSeF)2I3 under Hydrostatic Pressure at Room Temperature
    Kondo, Ryusuke
    Kagoshima, Seiichi
    Tajima, Naoya
    Kato, Reizo
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2009, 78 (11)