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A stereoselective synthesis of (+)-boronolide
被引:52
|作者:
Ghosh, AK
[1
]
Bilcer, G
[1
]
机构:
[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA
关键词:
D O I:
10.1016/S0040-4039(99)02246-7
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A stereoselective synthesis of (+)-boronolide is described. The key steps involve a stereoselective reduction of an oc-hydroxy ketone, allylation of an alpha-hydroxy aldehyde and a ring-closing olefin metathesis of a homoallylic alcohol derived acrylate ester utilizing Grubbs' catalyst. (C) 2000 Elsevier Science Ltd. All rights reserved.
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页码:1003 / 1006
页数:4
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