Synchrotron Radiation Study of Interconfigurational 5d-4f Luminescence of Pr3+ in KLuP2O7

被引：7
|
作者：
Trevisani, Mattia [1 ,2 ]
Ivanovskikh, Konstantin [3 ]
Piccinelli, Fabio [1 ,2 ]
Bettinelli, Marco [1 ,2 ]
机构：
[1] Univ Verona, Dept Biotechnol, Lab Luminescent Mat, I-37134 Verona, Italy
[2] UdR Verona, INSTM, I-37134 Verona, Italy
[3] Ural Fed Univ, Inst Phys & Technol, Ekaterinburg 62002, Russia
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 02期
关键词：
Pr3+; 5d-4f Luminescence; KLuP2O7; VUV Spectroscopy; Synchrotron Radiation; Scintillator; RARE-EARTH DIPHOSPHATES; DOUBLE PHOSPHATES; RE; LANTHANIDES; NA; LU; CS; RB;
D O I：
10.5560/ZNB.2014-3260
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The double phosphate KLuP2O7 doped with Pr3+ ions was prepared by solid-state reaction. The material obtained was characterized by powder X-ray diffraction. The luminescence spectroscopy and the excited state dynamics of this material were studied upon excitation with VUV synchrotron radiation. The 5d-4f emission of Pr3+ upon both direct and band gap excitation was detected and assigned. The decay kinetics of the Pr3+ 5d-4f emission is characterized by a decay time of about 20 ns and is nearly temperature independent within the range 8-300 K. Both dynamics and energy transfer peculiarities revealed in the study suggested good potentials for application of KLuP2O7:Pr3+ as a fast scintillator material.
引用
收藏
页码：205 / 209
页数：5
相关论文
共 50 条
  • [31] Shortwave Ultraviolet Persistent Luminescence of Sr2MgSi2O7: Pr3+
    Antuzevics, Andris
    Doke, Guna
    Krieke, Guna
    Rodionovs, Pavels
    Nilova, Dace
    Cirulis, Jekabs
    Fedotovs, Andris
    Rogulis, Uldis
    MATERIALS, 2023, 16 (05)
  • [32] 5d-4f Radioluminescence in Pr3+-doped K3YxLu1-x (PO4)2
    Carrasco, I.
    Bartosiewicz, K.
    Piccinelli, F.
    Nikl, M.
    Bettinelli, M.
    NANO-OPTICS: PRINCIPLES ENABLING BASIC RESEARCH AND APPLICATIONS, 2017, : 489 - 490
  • [33] VUV 5d-4f luminescence of Gd3+ and Lu3+ ions in the CaF2 host
    Makhov, V. N.
    Batygov, S. Kh.
    Dmitruk, L. N.
    Kirm, M.
    Vielhauer, S.
    Stryganyuk, G.
    PHYSICS OF THE SOLID STATE, 2008, 50 (09) : 1625 - 1630
  • [34] VUV 5d-4f luminescence of Gd3+ and Lu3+ ions in the CaF2 host
    V. N. Makhov
    S. Kh. Batygov
    L. N. Dmitruk
    M. Kirm
    S. Vielhauer
    G. Stryganyuk
    Physics of the Solid State, 2008, 50 : 1625 - 1630
  • [35] Luminescence characteristics of the Pr3+ ion in SrB4O7 and SrB6O10
    Rodnyi, PA
    Berezovskaya, IV
    Voloshinovskii, AS
    Stryganyuk, GB
    Potapov, AS
    OPTICS AND SPECTROSCOPY, 2003, 94 (04) : 550 - 555
  • [36] Luminescence characteristics of the Pr3+ ion in SrB4O7 and SrB6O10
    P. A. Rodnyĭ
    I. V. Berezovskaya
    A. S. Voloshinovskii
    G. B. Stryganyuk
    A. S. Potapov
    Optics and Spectroscopy, 2003, 94 : 550 - 555
  • [37] The effect of temperature on the 4f5d emission of Pr3+ in the Pr3+-doped SrAl12O19
    Shi-Qun, Qi
    Shi-Hua, Huang
    Fang-Tian, You
    Da-Wei, Wang
    Chang-Cheng, Gao
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28 (05) : 1012 - 1015
  • [38] Luminescence efficiency enhancement by impurity doping in SrIn2O4: Pr3+
    Yamamoto, Hajime
    Abe, Masashi
    Ogura, Manabu
    Mitsumine, Satoe
    Uheda, Kyota
    Okamoto, Shinji
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (01) : J15 - J20
  • [39] The 4f5d configuration and VUV absorption of Pr3+ in YPO4
    Huang, Shihua
    You, Fangtian
    Meng, Chunxia
    Wang, Dawei
    Tao, Ye
    Zhang, Guobin
    JOURNAL OF LUMINESCENCE, 2007, 122 (1-2) : 25 - 27
  • [40] Luminescence properties of Pr3+ doped 12CaO.7Al2O3 ceramics
    Mao, Y-Q
    Pu, Y-P
    Wei, J-F
    MATERIALS RESEARCH INNOVATIONS, 2011, 15 (04) : 260 - 263
12345