Silver-Catalyzed Isocyanide Insertion into N-H Bond of Ammonia: [5+1] Annulation to Quinazoline Derivatives

被引：30

作者：

Zhang, Lingjuan ^{[1
]}

Li, Juanjuan ^{[1
]}

Hu, Zhongyan ^{[2
]}

Dong, Jinhuan ^{[2
]}

Zhang, Xian-Ming ^{[1
]}

Xu, Xianxiu ^{[2
]}

机构：

[1] Shanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Magnet Mol & Magnet Informat Mat, Minist Educ, Linfen 041004, Peoples R China

[2] Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Coll Chem Chem Engn & Mat Sci,Minist Educ, Key Lab Mol & Nano Probes,Inst Mol & Nano Sci, Jinan 250014, Shandong, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 10期

关键词：

silver-catalyzed; 5+1] annulation; isocyanide insertion; quinazolines; quinazoline; 3-oxides; 2-SUBSTITUTED QUINAZOLINES; 3-COMPONENT SYNTHESIS; MIGRATORY INSERTION; OXIDATIVE AMINATION; ACCESS; MULTICOMPONENT; HETEROCYCLES; ISONITRILES; ACTIVATION; ROUTE;

D O I：

10.1002/adsc.201701623

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A silver-catalyzed [5+1] annulation of o-acylaryl isocyanides with ammonium acetate and hydroxlamine was developed for the efficient and practical synthesis of quinazolines and quinazoline 3-oxides in good to excellent yields, respectively. The domino process involved an unprecedented isocyanide insertion into the N-H bond of ammonia or hydroxylamine and followed by condensation reaction at ambient conditions.

引用

页码：1938 / 1942

页数：5

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