Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I)

被引：9

作者：

Duckett, SB ^{[1
]}

Gálvez-López, MD ^{[1
]}

Perutz, RN ^{[1
]}

Schott, D ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

DALTON TRANSACTIONS | 2004年 / 17期

关键词：

D O I：

10.1039/b407735k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of carbene complexes RhCl(CR'(2))(PR3)(2) (R=Ph, Tol, Me, R'=Ph and Tol) have been synthesised through direct reaction of photochemically generated free diarylcarbene with RhCl(CO)(PR3)(2). This route to carbene complexes demonstrates the reactivity of simple diarylcarbenes towards transition metal complexes. The reactivity of some of these complexes towards H-2, C2H4 and Et3SiH has been investigated.

引用

页码：2746 / 2749

页数：4

共 50 条

[21] Synthesis and characterization of square-planar palladium(II), platinum(II) and rhodium(I) complexes with a chiral pyridylphosphine hybrid ligand
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (07): : 1295 - 1299
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