Formation of Metastable Fragments around the Cl 2p Ionization Thresholds of HCl

被引：5

作者：

Hikosaka, Y. ^{[1
]}

Kaneyasu, T. ^{[1
]}

Shigemasa, E. ^{[1
]}

机构：

[1] Inst Mol Sci, UVSOR Facil, Okazaki, Aichi 4448585, Japan

来源：

JOURNAL OF THE KOREAN PHYSICAL SOCIETY | 2008年 / 53卷 / 06期

基金：

日本学术振兴会;

关键词：

Inner-shell excitation; Metastable; HCl;

D O I：

10.3938/jkps.53.3798

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Formation of metastable fragments has been investigated in the vicinity of the Cl 2p ionization thresholds of HCl Efficient productions of H* fragments with their counterpart of Cl(n+) ions are observed around the ionization thresholds. The formations of H*+Cl(n+) pairs result from the dissociation of high-Rydberg HCl(+) states that are populated either by spectator Auger decay from the inner-shell excited states or by the recapture of slow photoelectrons into the Rydberg orbitals. In addition, H* fragments are shown to be produced through the dissociation of HCl(2+) states formed via normal Auger decay of the Cl 2p core-hole states.

引用

页码：3798 / 3801

页数：4

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