A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde

被引：6

作者：

Benniston, Andrew C. ^{[1
]}

Sirbu, Dumitru ^{[2
]}

Turta, Constantin ^{[2
]}

Probert, Michael R. ^{[3
]}

Clegg, William ^{[3
]}

机构：

[1] Newcastle Univ, Sch Chem, Mol Photon Lab, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova

[3] Newcastle Univ, Sch Chem, Crystallog Lab, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 28期

基金：

英国工程与自然科学研究理事会;

关键词：

Ferrocene; Oxidation; Desymmetrization; Carboxylic acid; Michael addition; FERROCENES; COMPLEXES; SPECTRA;

D O I：

10.1016/j.tetlet.2014.05.040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple chromatography-free method for desymmetrizing ferrocene is described starting from the readily available dialdehyde. Oxidation of 1,1'-ferrocenedicarboxaldehyde in a water/acetonitrile mixture with KMnO4 produced 1'-formyl-ferrocenecarboxylic acid. The same reaction carried out in a water/acetone mixture produced 1'-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：3777 / 3780

页数：4

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