A simple method for desymmetrizing 1,1′-ferrocenedicarboxaldehyde

被引：6
|
作者：
Benniston, Andrew C. [1 ]
Sirbu, Dumitru [2 ]
Turta, Constantin [2 ]
Probert, Michael R. [3 ]
Clegg, William [3 ]
机构：
[1] Newcastle Univ, Sch Chem, Mol Photon Lab, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
[2] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova
[3] Newcastle Univ, Sch Chem, Crystallog Lab, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 28期
基金：
英国工程与自然科学研究理事会;
关键词：
Ferrocene; Oxidation; Desymmetrization; Carboxylic acid; Michael addition; FERROCENES; COMPLEXES; SPECTRA;
D O I：
10.1016/j.tetlet.2014.05.040
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple chromatography-free method for desymmetrizing ferrocene is described starting from the readily available dialdehyde. Oxidation of 1,1'-ferrocenedicarboxaldehyde in a water/acetonitrile mixture with KMnO4 produced 1'-formyl-ferrocenecarboxylic acid. The same reaction carried out in a water/acetone mixture produced 1'-[(E)-3-oxo-but-1-enyl]-ferrocenecarboxylic acid. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3777 / 3780
页数：4
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