Asymmetric synthesis of bicyclopropane derivatives

被引：19
|
作者：
Barrett, AGM [1 ]
Doubleday, WW [1 ]
Tustin, GJ [1 ]
机构：
[1] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523
来源：
TETRAHEDRON | 1996年 / 52卷 / 48期
关键词：
D O I：
10.1016/S0040-4020(96)00934-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Both syn- and anti-bicyclopropane derivatives have been efficiently prepared with good relative and absolute stereocontrol using reagent controlled asymmetric cyclopropanation reactions. Double Simmons-Smith cyclopropanation of 2,4-dien-1-ols stereoselectively gave the corresponding anti-bicyclopropane derivatives. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：15325 / 15338
页数：14
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