Self-assembled monolayers on electroless gold impart pH-responsive transport of ions in porous membranes

被引：95
|
作者：
Hou, ZZ [1 ]
Abbott, NL [1 ]
Stroeve, P [1 ]
机构：
[1] Univ Calif Davis, Natl Sci Fdn Ctr Polym Interfac & Macromol Assembl, CPIMA, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
来源：
LANGMUIR | 2000年 / 16卷 / 05期
关键词：
D O I：
10.1021/la991045k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The surface properties of pore walls in polycarbonate track-etched (PCTE) membranes was modified by formation of self-assembled monolayers (SAMs) from ω-substituted thiols onto electroless gold deposited on the pore walls of the membrane. SAMs formed from a carboxylic acid-functionalized thiol impart to the membrane high pH-dependence of ionic fluxes across the membrane. The surface-modification procedure described may provide an alternative route to prepare porous ion-selective membranes.
引用
收藏
页码：2401 / 2404
页数：4
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