The room temperature crystal structure of the perovskite Pr0.5Sr0.5MnO3

被引：41
|
作者：
Argyriou, DN
Hinks, DG
Mitchell, JF
Potter, CD
Schultz, AJ
Young, DM
Jorgensen, JD
Bader, SD
机构：
[1] ARGONNE NATL LAB,SCI & TECHNOL CTR SUPERCONDUCTIV,ARGONNE,IL 60439
[2] ARGONNE NATL LAB,INTENSE PULSED NEUTRON SOURCE,ARGONNE,IL 60439
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1996年 / 124卷 / 02期
关键词：
D O I：
10.1006/jssc.1996.0253
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using both powder and single crystal neutron diffraction we have determined the room temperature structure of Pr0.5Sr0.5MnO3 from melt-grown crystalline material. Contrary to previous measurements on polycrystalline samples we find the room temperature structure of Pr0.5Sr0.5MnO3 is tetragonal, space group F4/mmc (a = 7.64093(5) Angstrom, c = 7.79104(8) Angstrom), The structure of Pr0.5Sr0.5MnO3 is related to the ideal primitive cubic perovskite structure by a single correlated rotation of MnO6 octahedra about the c axis. We find that MnO6 octahedra exhibit a small Jahn-Teller distortion (Delta(Mn-O) approximate to 0.02 Angstrom). (C) 1996 Academic Press, Inc.
引用
收藏
页码：381 / 384
页数：4
相关论文
共 50 条
  • [41] Influence of the deposition temperature on the metal-to-insulator transition in Pr0.5Sr0.5MnO3 thin films
    Prellier, W
    Mercey, B
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (01) : 172 - 174
  • [42] The effect of post-annealing on the structure and magnetotransport properties of Pr0.5Sr0.5MnO3 thin film
    Chen, Liping
    Zeng, Jiali
    Li, Miao
    Tang, Zhenhua
    Gao, Ju
    AIP ADVANCES, 2017, 7 (05):
  • [43] Tailored inverse magnetocaloric effect of Pr0.5Sr0.5MnO3 manganite with Eu substitution
    Yang, Hangfu
    Huang, Xiani
    Wu, Qiong
    Luo, Xinyao
    Wang, Qingwei
    Fang, Jieyang
    Yu, Nengjun
    Pan, Minxiang
    Ge, Hongliang
    MATERIALS CHEMISTRY AND PHYSICS, 2021, 267
  • [44] Resonant photoemission spectroscopy studies of the magnetic phase transitions in Pr0.5Sr0.5MnO3
    Pal, P.
    Dalai, M. K.
    Sekhar, B. R.
    Ulfat, I.
    Merz, M.
    Nagel, P.
    Schuppler, S.
    PHYSICA B-CONDENSED MATTER, 2011, 406 (18) : 3519 - 3523
  • [45] Structural and magnetic properties of tetragonal and orthorhombic Pr0.5Sr0.5MnO3 thin films
    Chen, X. G.
    Ma, X. B.
    Yang, Y. B.
    Liu, S. Q.
    Du, H. L.
    Han, J. Z.
    Wang, C. S.
    Yang, Y. C.
    Yang, J. B.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2012, 45 (31)
  • [46] Magnetocaloric effect studying by means of theoretical models in Pr0.5Sr0.5MnO3 manganite
    Hsini, Mohamed
    Hcini, Sobhi
    Zemni, Sadok
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2018, 466 : 368 - 375
  • [47] Transport and magnetic properties of bulk and epitaxial thin film of Pr0.5Sr0.5MnO3
    Roy, B
    Poddar, A
    Das, S
    Gmelin, E
    JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 326 (1-2) : 317 - 320
  • [48] Thermoelectric power of Pr0.5Sr0.5MnO3 with Ru substitution at the Mn-site
    Kim, JS
    Kim, DC
    McIntosh, GC
    Kim, BJ
    Kim, YC
    Maignan, A
    Raveau, B
    Park, YW
    SUPERCONDUCTING AND RELATED OXIDES: PHYSICS AND NANOENGINEERING V, 2002, 4811 : 266 - 276
  • [49] Reply to "Comment on 'Tetragonal to monoclinic transition in the metallic antiferromagnet Pr0.5Sr0.5MnO3"
    Frontera, C
    García-Muñoz, JL
    Llobet, A
    Ritter, C
    PHYSICAL REVIEW B, 2000, 62 (10): : 6822 - 6824
  • [50] Interparticle interaction and crossover in critical lines on field-temperature plane in Pr0.5Sr0.5MnO3 nanoparticles
    Pramanik, A. K.
    Banerjee, A.
    PHYSICAL REVIEW B, 2010, 82 (09)
12345