Thioacylation reactions for the surface functionalization of phosphorus-containing dendrimers

被引:8
|
作者
Marchand, P
Griffe, L
Caminade, AM
Majoral, JP
Destarac, M
Leising, F
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
[2] Ctr Rech Aubervilliers, F-93308 Aubervilliers, France
关键词
D O I
10.1021/ol049720r
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The functionalization of phosphorus-containing dendrimers was easily achieved through thioacylation reactions involving new dendrimers capped with dithioester end groups and various functionalized amines. These reactions were successfully applied to the first generation (12 end groups) and the third generation of the dendrimer (48 end groups) and allowed their functionalization by various primary or secondary amines, alcohols, glycols, and azides.
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页码:1309 / 1312
页数:4
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