Electrochemical characteristics of nanotubes formed on Ti-Nb alloys

被引:90
|
作者
Jang, Seung-Hyun [1 ,2 ]
Choe, Han-Cheol [1 ,2 ]
Ko, Yeong-Mu [1 ,2 ,4 ]
Brantley, William A. [3 ]
机构
[1] Chosun Univ, Dept Dent Mat, Kwangju, South Korea
[2] Chosun Univ, Res Ctr Nanointerface Activat Biomat, Coll Dent, Stage Brain Korea 21 Coll Dent 2, Kwangju, South Korea
[3] Ohio State Univ, Coll Dent, Columbus, OH 43210 USA
[4] Chosun Univ, Res Ctr Oral Dis Regulat Aged, Coll Dent, Kwangju, South Korea
关键词
Electrochemical anodization; Nanotube; Corrosion behavior; Ti-xNb alloy; TITANIUM-ALLOYS; OXIDIZED TITANIUM; TI45NB ALLOY; SURFACE;
D O I
10.1016/j.tsf.2009.03.166
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Titanium and Ti alloys have been used extensively as bone-implant materials due to their high strength-to-weight ratio, good biocompatibility and excellent corrosion resistance. In this work we have investigated the effects of the beta-stabilizing element Nb on the morphology of nanotubes formed on Ti-xNb alloys using 1.0 M H3PO4 electrolyte containing 0.8 wt.% NaF and various electrochemical methods. Oxide layers consisting of highly ordered nanotubes with a wide range of diameters (approximately 55-220 nm) and lengths (approximately 730 nm-2 mu m) can be formed on alloys in the Ti-xNb system as a function of Nb content The nanotubes formed on the Ti-Nb alloy surface were transformed from the anatase to rutile structure of titanium oxide. The titanium oxide nanotube surface was observed to have lower corrosion resistance in 0.9% NaCl solution compared to titanium oxides surfaces on Ti-xNb alloys without the nanotube morphology. (c) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:5038 / 5043
页数:6
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