Synthesis of copper nanocolloids using a continuous flow based microreactor

被引：19
|
作者：
Xu, Lei [1 ,2 ]
Peng, Jinhui [1 ]
Srinivasakannan, C. [3 ]
Chen, Guo [1 ]
Shen, Amy Q. [2 ,4 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Met & Energy Engn, State Key Lab Complex Nonferrous Met Resources Cl, Kunming 650093, Peoples R China
[2] Univ Washington, Mech Engn, Seattle, WA 98195 USA
[3] Petr Inst, Chem Engn Program, Abu Dhabi, U Arab Emirates
[4] Grad Univ, Okinawa Inst Technol, Micro Bio Nanofluid Unit, Okinawa, Japan
来源：
APPLIED SURFACE SCIENCE | 2015年 / 355卷
基金：
中国国家自然科学基金;
关键词：
Microreactor; Synthesis; Copper nanocolloids; Sodium borohydride reduction; MICROFLUIDIC SYNTHESIS; SILVER NANOPARTICLES; METAL NANOPARTICLES; FABRICATION; DESIGN; SIZE;
D O I：
10.1016/j.apsusc.2015.07.070
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The copper (Cu) nanocolloids were prepared by sodium borohydride (NaBH4) reduction of metal salt solutions in a T-shaped microreactor at room temperature. The influence of NaBH4 molar concentrations on copper particle's diameter, morphology, size distribution, and elemental compositions has been investigated by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The ultraviolet-visible spectroscopy (UV-vis) was used to verify the chemical compounds of nanocolloids and estimate the average size of copper nanocolloids. The synthesized copper nanocolloids were uniform in size and non-oxidized. A decrease in the mean diameter of copper nanocolloids was observed with increasing NaBH4 molar concentrations. The maximum mean diameter (4.25 nm) occurred at the CuSO4/NaBH4 molar concentration ratio of 1:2. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：1 / 6
页数：6
相关论文
共 50 条
  • [31] A continuous flow microreactor as a practical tool for the synthesis of active pharmaceutical ingredients
    Bhaskar, K. Vijaya
    Rashed, Mohammad
    Bhat, K. Subrahmanya
    Lee, Jechan
    Kim, Ki-Hyun
    Buruga, Kezia
    PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2024, 192 : 437 - 449
  • [32] Continuous flow microreactor for protein PEGylation
    Madadkar, P.
    Selvaganapathy, P. R.
    Ghosh, R.
    BIOMICROFLUIDICS, 2018, 12 (04):
  • [33] Continuous-flow synthesis of lithium carbonate in a microreactor system based on spent LIBs recycling process
    Zhou, Yiwei
    Zhang, Jingwei
    Chen, Zhuo
    Xu, Jianhong
    RESULTS IN ENGINEERING, 2023, 20
  • [34] Single-step radiofluorination of peptides using continuous flow microreactor
    Selivanova, Svetlana V.
    Mu, Linjing
    Ungersboeck, Johanna
    Stellfeld, Timo
    Ametamey, Simon M.
    Schibli, Roger
    Wadsak, Wolfgang
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (19) : 3871 - 3874
  • [35] Mixing control in a continuous-flow microreactor using electro-osmotic flow
    Siraev, Ramil
    Ilyushin, Pavel
    Bratsun, Dmitry
    MATHEMATICAL MODELLING OF NATURAL PHENOMENA, 2021, 16
  • [36] Synthesis of Lobeglitazone intermediates seeking for continuous drug production in flow capillary microreactor
    Silva, Renan Rodrigues de Oliveira
    Calvo, Paulo Victor Cuesta
    Merfels, Christian Adrian
    Lima, Mikael Vitor Rodrigues
    Santana, Harrson S.
    Converti, Attilio
    Palma, Mauri Sergio Alves
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2022, 116 : 239 - 249
  • [37] Selective Hydrogenation Reaction: Utilizing a Microreactor for Continuous Flow Synthesis of Nickel Nanoparticles
    Srivastava, Vivek
    LETTERS IN ORGANIC CHEMISTRY, 2024, 21 (09) : 790 - 803
  • [38] Ultrafast synthesis of isoquercitrin by enzymatic hydrolysis of rutin in a continuous-flow microreactor
    Wang, Jun
    Gong, An
    Gu, Shuangshuang
    Cui, Hongsheng
    Wu, Xiangyang
    Journal of the Serbian Chemical Society, 2014, 79 (11)
  • [39] Process intensification of copper chromite (CuCr2O4) nanoparticle production using continuous flow microreactor
    Appalakutti, Sumanth
    Sonawane, Shirish
    Bhanvase, Bharat A.
    Mittal, Vikas
    Ashokkumar, Muthupandian
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2015, 89 : 28 - 34
  • [40] Toward the Efficient Synthesis of Pseudoionone from Citral in a Continuous-Flow Microreactor
    Zhou, Feng
    Liu, Hongchen
    Wen, Zhenghui
    Zhang, Boyu
    Chen, Guangwen
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (33) : 11288 - 11298
12345