Magnetic properties of anion-radical salt [FeII(dipy)3](TCNQ)4•(CH3)2CO

被引：2
|
作者：
Vasylets, G. [1 ]
Starodub, V. A. [2 ]
Feher, A. [3 ]
Kajnakova, M. [3 ]
Zboril, R. [4 ]
Tucek, J. [4 ]
Metz, H. [5 ]
Potocnak, I. [6 ]
机构：
[1] Kharkov Natl Univ, Fac Chem, UA-61022 Kharkov, Ukraine
[2] Jan Kochanowski Univ, Inst Chem, PL-25406 Kielce, Poland
[3] Safarik Univ, Inst Phys, Kosice 04154, Slovakia
[4] Reg Ctr Adv Technol & Mat, Olomouc 77146, Czech Republic
[5] Univ Halle Wittenberg, Inst Pharm, D-06120 Halle, Saale, Germany
[6] Safarik Univ, Inst Chem, Kosice 04154, Slovakia
来源：
SYNTHETIC METALS | 2014年 / 194卷
关键词：
Tetracyanoquinodimethane; Mossbauer spectroscopy; Magnetic susceptibility; SPIN-CROSSOVER; MOSSBAUER; COMPLEXES; IRON;
D O I：
10.1016/j.synthmet.2014.04.011
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Magnetic properties of anion-radical TCNQ salt [Fe(dipy)(3)](TCNQ)(4)center dot(CH3)(2)CO have been investigated (dipy is 2,2'-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramerized (diamagnetic) and partly dimerized (paramagnetic). Due to Mossbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：7 / 10
页数：4
相关论文
共 50 条
  • [41] The thermoelastic properties of [N(CH3)4]2ZnBr4 and [N(CH3)4]2MnBr4
    López-Echarri, A
    Ruiz-Larrea, I
    Fraile-Rodríguez, A
    PHASE TRANSITIONS, 2000, 71 (02) : 101 - 111
  • [42] Production of CH(A~2△) by multi-photon dissociation of (CH3)2CO, CH3NO2, CH2Br2, and CHBr3 at 213 nm
    李胜强
    许亮
    陈扬骎
    邓联忠
    印建平
    Chinese Physics B, 2014, 23 (08) : 331 - 336
  • [43] Structure of heteroassociates formed in the HF-(CH3)2CO binary liquid system
    Tarakanova, E. G.
    Yukhnevich, G. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (03) : 495 - 502
  • [44] Structure of heteroassociates formed in the HF-(CH3)2CO binary liquid system
    E. G. Tarakanova
    G. V. Yukhnevich
    Journal of Structural Chemistry, 2012, 53 : 495 - 502
  • [45] The 'globule-globule' hybrid dicarbaborane-polyoxometallate salt, [C2B10H11CH2NHCH(CH3)2]4[W10O32][H2O]2[(CH3)2CO]4
    Macías, R
    Kennedy, JD
    Thornton-Pett, M
    Román, P
    CRYSTENGCOMM, 2003, : 93 - 95
  • [46] Structure, IR and Mossbauer spectra, and magnetic properties of [Fe2CoO(CH3COO)6(3-Cl-Py)3]•1/4 3-Cl-Py• 1/4(CH3)2CO• 1/2H2O
    Jovmir, TC
    Turta, CI
    Shova, SG
    Simonov, YA
    Gdaniec, M
    Bulgac, II
    Cadelnic, IG
    Filoti, G
    JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 40 (06) : 905 - 913
  • [47] EXCESS MOLAR VOLUMES OF [XCH(3)(CH2)(4)OH+(1-X)(CH3COCH(CH3)CH3 OR CH3COCH2CH(CH3)CH3 OR CH3CH(OH)CH(CH3)CH3 OR CH3CH(CH3)OCOCH3 CH3CH2CH(CH3)OCOCH3 OR CH3(CH2)(2)CH(CH3)OCOCH3 OR CH3CH(CH3)CH(CH3)CH3)] AT TEMPERATURES FROM 288.15 K TO 328.15 K AND EACH AT SATURATION PRESSURE
    KUMAR, P
    BHAISARE, MP
    KUDCHADKER, AP
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (02): : 197 - 203
  • [48] A novel anion-radical salt (N-Et-2.5-di-Me-Pz)(TCNQ)(2) (Pz is pyrazine)
    Ziolkovskiy, D. V.
    Kazheva, O. N.
    Shilov, G. V.
    Dyachenko, O. A.
    Kravchenko, A. V.
    Khotkevich, A. V.
    Starodub, V. A.
    FUNCTIONAL MATERIALS, 2006, 13 (01): : 119 - 124
  • [49] Structure, IR and Mössbauer spectra, and magnetic properties of [Fe2CoO(CH3COO)6(3-CI-Py)3]· 1/4· 3-Cl-Py· 1/4(CH3)2CO· 1/2H2O
    T. C. Jovmir
    C. I. Turta
    S. G. Shova
    Yu. A. Simonov
    M. Gdaniec
    I. I. Bulgac
    I. G. Cadelnic
    G. Filoti
    Journal of Structural Chemistry, 1999, 40 : 905 - 913
  • [50] MOSSBAUER EFFECT STUDIES OF (CH3)4SN3FE4(CO)16 AND (CH3)4SN2FE2(CO)8
    JONES, MT
    INORGANIC CHEMISTRY, 1967, 6 (06) : 1249 - &
12345