Synthesis and Characterization of Cu-Doped Zirconium Titanate as A Potential Visible-Light Responsive Photocatalyst

被引:6
|
作者
Andita, Katarina Rachma [1 ]
Kurniawan, Rian [1 ]
Syoufian, Akhmad [1 ]
机构
[1] Univ Gadjah Mada, Fac Math & Nat Sci, Dept Chem, Sekip Utara 55281, Yogyakarta, Indonesia
关键词
copper; dopant; Cu-doped ZrTiO4; photocatalyst; sol-gel; TIO2; ZRO2; DEGRADATION; FILMS;
D O I
10.22146/ijc.39778
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis and characterization of Cu-doped zirconium titanate as a potential visible-light responsive photocatalyst had been conducted. Titanium tetraisopropoxide (TTIP) was used as a precursor of Ti source, reacted to ZrO2 powder and CuSO4 center dot 5H(2)O with various Cu concentrations of 0, 1, 3, 5, 7 and 9% (w/w) by sol-gel method. Zirconium titanate with Cu concentration of 5% was calcined at various temperatures of 500, 700 and 900 degrees C. All materials were characterized by using XRD, FTIR, SRUV, and SEM-EDX. The characterization proved that the materials were potential as a model of visible-light responsive photocatalyst. Composite with optimum bandgap energy (E-g) was obtained at 5% Cu content after 500 degrees C with an absorption edge wavelength of 431.93 nm and the bandgap of 2.87 eV.
引用
收藏
页码:761 / 766
页数:6
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