Efficient diastereoselective intermolecular rhodium-catalyzed C-H amination

被引：218
|
作者：
Liang, Chungen
Robert-Pedlard, Fabien
Fruit, Corinne
Mueller, Paul
Dodd, Robert H.
Dauban, Philippe
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
[2] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期
关键词：
amination; C-H insertion; hypervalent iodine; nitrenes; rhodium;
D O I：
10.1002/anie.200601248
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Successful matchmaking: The combination of a chiral nitrene precursor with a chiral rhodium(II) catalyst is the key factor that allows efficient intermolecular regioselective C-H amination. Good-to-excellent yields and excellent diastereoselectivities can be obtained with a stoichiometric amount of the C-H bond containing substrate. nttl = N-1,8-naphthoyl-tert-leucine. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4641 / 4644
页数：4
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